Rh(III)-Catalyzed Annulation of Boc-Protected Benzamides with Diazo Compounds: Approach to Isocoumarins
2019-03
Source PublicationMOLECULES
ISSN1420-3049
Volume24Issue:5
Status已发表
DOI10.3390/molecules24050937
AbstractA mild rhodium-catalyzed annulation of Boc-protected benzamides with diazo compounds via C-C/C-O bond formation has been explored. In the presence of [Cp*RhCl2](2), AgSbF6 and Cs2CO3, Boc-protected benzamides can be effectively annulated to yield isocoumarins in 0.5-2 h.
Keywordrhodium annulation Boc-protected benzamides
Indexed BySCI ; SCIE
Language英语
Funding ProjectMajor Project of Chinese National Programs for Fundamental Research and Development[2015CB910304]
WOS Research AreaBiochemistry & Molecular Biology ; Chemistry
WOS SubjectBiochemistry & Molecular Biology ; Chemistry, Multidisciplinary
WOS IDWOS:000462662900113
PublisherMDPI
WOS KeywordALPHA-PYRONES ; CATALYZED-REACTIONS ; BOND FORMATION ; BENZOIC-ACIDS ; C-C ; CYCLIZATION ; AMIDES ; OXIDATION ; ALKYNES ; LIGAND
Original Document TypeArticle
Citation statistics
Document Type期刊论文
Identifierhttps://kms.shanghaitech.edu.cn/handle/2MSLDSTB/34178
Collection生命科学与技术学院_硕士生
生命科学与技术学院_特聘教授组_柳红组
Corresponding AuthorLiu, Hong
Affiliation
1.Chinese Acad Sci, Shanghai Inst Mat Med, State Key Lab Drug Res, 555 Zuchongzhi Rd, Shanghai 201203, Peoples R China
2.Univ Chinese Acad Sci, 19A Yuquan Rd, Beijing 100049, Peoples R China
3.ShanghaiTech Univ, Sch Life Sci & Technol, 100 Haike Rd, Shanghai 201210, Peoples R China
First Author AffilicationSchool of Life Science and Technology
Corresponding Author AffilicationSchool of Life Science and Technology
Recommended Citation
GB/T 7714
Dong, Guangyu,Li, Chunpu,Liu, Hong. Rh(III)-Catalyzed Annulation of Boc-Protected Benzamides with Diazo Compounds: Approach to Isocoumarins[J]. MOLECULES,2019,24(5).
APA Dong, Guangyu,Li, Chunpu,&Liu, Hong.(2019).Rh(III)-Catalyzed Annulation of Boc-Protected Benzamides with Diazo Compounds: Approach to Isocoumarins.MOLECULES,24(5).
MLA Dong, Guangyu,et al."Rh(III)-Catalyzed Annulation of Boc-Protected Benzamides with Diazo Compounds: Approach to Isocoumarins".MOLECULES 24.5(2019).
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