Construction of Vinyl-Substituted N-Heterocycles via Rh(III)- Catalyzed C-H Functionalization/Annulation of Pyrazolidinones
2023
发表期刊ADVANCED SYNTHESIS & CATALYSIS
ISSN1615-4150
EISSN1615-4169
发表状态已发表
DOI10.1002/adsc.202201065
摘要

The transition-metal-catalyzed C-H activation and annulation reactions of pyrazolidinones with 4-vinyl-1,3-dioxolan-2-one or vinylene carbonate are described herein. This protocol provided two types of pyrazolo[1,2-a]cinnolines as essential assets for the development of bioactive compounds, and the synthetic practicality was performed and explained with 44 examples. The possible mechanism of these two reactions is proposed based on preliminary studies and previous reports, and no oxidant was added to both reactions.

关键词annulation reactions C-H activation pyrazolidinone Rh(III)-catalyzed
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收录类别SCI ; SCOPUS
语种英语
资助项目National Natural Science Foundation of China[
WOS研究方向Chemistry
WOS类目Chemistry, Applied ; Chemistry, Organic
WOS记录号WOS:000919009700001
出版者WILEY-V C H VERLAG GMBH
引用统计
被引频次:9[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符https://kms.shanghaitech.edu.cn/handle/2MSLDSTB/278844
专题生命科学与技术学院
生命科学与技术学院_特聘教授组_柳红组
生命科学与技术学院_博士生
通讯作者Yang, Zhao; Liu, Hong; Wang, Jiang
作者单位
1.Lingang Lab, Shanghai 200031, Peoples R China
2.ShanghaiTech Univ, Sch Life Sci & Technol, Shanghai 200031, Peoples R China
3.China Pharmaceut Univ, 639 Longmian Ave, Nanjing 211198, Peoples R China
4.Chinese Acad Sci, Shanghai Inst Mat Med, State Key Lab Drug Res, 555 Zu Chong Zhi Rd, Shanghai 201203, Peoples R China
5.Nanjing Univ Chinese Med, Sch Chinese Mat Med, Nanjing 210023, Peoples R China
第一作者单位生命科学与技术学院
通讯作者单位生命科学与技术学院
推荐引用方式
GB/T 7714
Zhang, Shurui,Hu, Shulei,Wang, Kean,et al. Construction of Vinyl-Substituted N-Heterocycles via Rh(III)- Catalyzed C-H Functionalization/Annulation of Pyrazolidinones[J]. ADVANCED SYNTHESIS & CATALYSIS,2023.
APA Zhang, Shurui,Hu, Shulei,Wang, Kean,Yang, Zhao,Liu, Hong,&Wang, Jiang.(2023).Construction of Vinyl-Substituted N-Heterocycles via Rh(III)- Catalyzed C-H Functionalization/Annulation of Pyrazolidinones.ADVANCED SYNTHESIS & CATALYSIS.
MLA Zhang, Shurui,et al."Construction of Vinyl-Substituted N-Heterocycles via Rh(III)- Catalyzed C-H Functionalization/Annulation of Pyrazolidinones".ADVANCED SYNTHESIS & CATALYSIS (2023).
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