Sulfoximines-Assisted Rh(III)-Catalyzed C-H Activation and Intramolecular Annulation for the Synthesis of Fused Isochromeno-1,2-Benzothiazines Scaffolds under Room Temperature

doi:10.3390/molecules25112515

	Sulfoximines-Assisted Rh(III)-Catalyzed C-H Activation and Intramolecular Annulation for the Synthesis of Fused Isochromeno-1,2-Benzothiazines Scaffolds under Room Temperature
	Wang, Bao1,2,3,4 ; Han, Xu 1,2,3; Li, Jian 1,2; Li, Chunpu 1,2,3; Liu, Hong1,2,3,4
	2020-06
Source Publication	MOLECULES
ISSN	1420-3049
EISSN	1420-3049
Volume	25 Issue:11
Status	已发表
DOI	10.3390/molecules25112515
Abstract	A mild and facile Cp*Rh(III)-catalyzed C-H activation and intramolecular cascade annulation protocol has been proposed for the furnishing of highly fused isochromeno-1,2-benzothiazines scaffolds using S-phenylsulfoximides and 4-diazoisochroman-3-imine as substrates under room temperature. This method features diverse substituents and functional groups tolerance and relatively mild reaction conditions with moderate to excellent yields. Additionally, retentive configuration of sulfoximides in the conversion has been verified.
Keyword	sulfoximide C-H activation benzothiazine rhodium
URL	查看原文
Indexed By	SCI ; SCIE
Language	英语
Funding Project	National Natural Science Foundation of China[21672232][21977106][81620108027] ; National S&T Major Projects[2018ZX09711002] ; Strategic Priority Research Program of the Chinese Academy of Sciences[XDA12040217]
WOS Research Area	Biochemistry & Molecular Biology ; Chemistry
WOS Subject	Biochemistry & Molecular Biology ; Chemistry, Multidisciplinary
WOS ID	WOS:000553858800052
Publisher	MDPI
WOS Keyword	CATALYZED IMINATION ; ONE-POT ; 1,2-BENZOTHIAZINES ; SULFOXIDES ; SULFIDES ; ALKYNES
Original Document Type	Article
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Document Type	期刊论文
Identifier	https://kms.shanghaitech.edu.cn/handle/2MSLDSTB/122958
Collection	生命科学与技术学院_博士生生命科学与技术学院_特聘教授组_柳红组
Corresponding Author	Li, Chunpu; Liu, Hong
Affiliation	1.Chinese Acad Sci, Shanghai Inst Mat Med, State Key Lab Drug Res, 555 Chong Zhi Rd, Shanghai 201203, Peoples R China 2.Chinese Acad Sci, Shanghai Inst Mat Med, CAS Key Lab Receptor Res, 555 Chong Zhi Rd, Shanghai 201203, Peoples R China 3.Univ Chinese Acad Sci, 19A Yuquan Rd, Beijing 100049, Peoples R China 4.ShanghaiTech Univ, Sch Life Sci & Technol, 100 Haike Rd, Shanghai 201210, Peoples R China
First Author Affilication	School of Life Science and Technology
Corresponding Author Affilication	School of Life Science and Technology
Recommended Citation GB/T 7714	Wang, Bao,Han, Xu,Li, Jian,et al. Sulfoximines-Assisted Rh(III)-Catalyzed C-H Activation and Intramolecular Annulation for the Synthesis of Fused Isochromeno-1,2-Benzothiazines Scaffolds under Room Temperature[J]. MOLECULES,2020,25(11).
APA	Wang, Bao,Han, Xu,Li, Jian,Li, Chunpu,&Liu, Hong.(2020).Sulfoximines-Assisted Rh(III)-Catalyzed C-H Activation and Intramolecular Annulation for the Synthesis of Fused Isochromeno-1,2-Benzothiazines Scaffolds under Room Temperature.MOLECULES,25(11).
MLA	Wang, Bao,et al."Sulfoximines-Assisted Rh(III)-Catalyzed C-H Activation and Intramolecular Annulation for the Synthesis of Fused Isochromeno-1,2-Benzothiazines Scaffolds under Room Temperature".MOLECULES 25.11(2020).

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