Site-selective Csp(3)-H aryloxylation of natural product Tanshinone IIA and its analogues
2017-05-10
发表期刊TETRAHEDRON LETTERS (IF:1.5[JCR-2023],1.6[5-Year])
ISSN0040-4039
卷号58期号:19页码:1822-1825
发表状态已发表
DOI10.1016/j.tetlet.2017.03.078
摘要A novel catalyst-free Csp(3)-H aryloxylation approach allowing for rapid installation of a wide range of aryloxyl groups regioselectively at the C-4 position of Tanshinone IIA under simple and mild conditions was developed. This unique protocol exhibited atom-/step-economy, low cost, high efficiency and robust functional-group tolerance, which will greatly facilitate to diversify the A-ring of the bioactive natural product. (C) 2017 Elsevier Ltd. All rights reserved.
关键词Natural product Tanshinone IIA Chemical modification Aryloxylation C-H activation
收录类别SCI ; IC ; CCR
语种英语
资助项目"Personalized Medicines Molecular Signature-based Drug Discovery and Development", Strategic Priority Research Program of the Chinese Academy of Sciences[XDA12020320]
WOS研究方向Chemistry
WOS类目Chemistry, Organic
WOS记录号WOS:000401204400004
出版者PERGAMON-ELSEVIER SCIENCE LTD
WOS关键词SALVIA-MILTIORRHIZA BUNGE ; VASODILATIVE ACTIVITY ; OXIDATIVE STRESS ; DERIVATIVES ; ABSORPTION ; ACTIVATION ; EXPRESSION
原始文献类型Article
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文献类型期刊论文
条目标识符https://kms.shanghaitech.edu.cn/handle/2MSLDSTB/1374
专题生命科学与技术学院
生命科学与技术学院_特聘教授组_张翱组
生命科学与技术学院_博士生
通讯作者Ding, Chunyong
作者单位
1.Univ Sci & Technol China, Nano Sci & Technol Inst, Suzhou 215123, Peoples R China
2.ShanghaiTech Univ, Shanghai 20120, Peoples R China
3.Chinese Acad Sci, Shanghai Inst Mat Med, CAS Key Lab Receptor Res Synthet Organ & Med Chem, Shanghai 201203, Peoples R China
4.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
Liang, Bing,Yu, Shujuan,Li, Jie,et al. Site-selective Csp(3)-H aryloxylation of natural product Tanshinone IIA and its analogues[J]. TETRAHEDRON LETTERS,2017,58(19):1822-1825.
APA Liang, Bing.,Yu, Shujuan.,Li, Jie.,Wang, Fan.,Liang, Gaolin.,...&Ding, Chunyong.(2017).Site-selective Csp(3)-H aryloxylation of natural product Tanshinone IIA and its analogues.TETRAHEDRON LETTERS,58(19),1822-1825.
MLA Liang, Bing,et al."Site-selective Csp(3)-H aryloxylation of natural product Tanshinone IIA and its analogues".TETRAHEDRON LETTERS 58.19(2017):1822-1825.
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