Supercritical CO2 foaming of radiation crosslinked polypropylene/high-density polyethylene blend: Cell structure and tensile property
2017-12
发表期刊RADIATION PHYSICS AND CHEMISTRY (IF:2.8[JCR-2023],2.6[5-Year])
ISSN0969-806X
卷号141页码:276-283
发表状态已发表
DOI10.1016/j.radphyschem.2017.07.028
摘要A blend of isotactic polypropylene (PP) with high-density polyethylene (HDPE) in different PP/HDPE ratios was irradiated by gamma-ray to induce cross-linking and then foamed using supercritical carbon dioxide (scCO(2)) as a blowing agent. Radiation effect on the melting point and crystallinity were analyzed in detail. The average cell diameter and cell density were compared for PP/HDPE foams prepared under different conditions. The optimum absorbed dose for the scCO(2) foaming of PP/HDPE in terms of foaming ability and cell structure was 20 kGy. Tensile measurements showed that the elongation at break and tensile strength at break of the crosslinked PP/HDPE foams were higher than the non-crosslinked ones. Of particular interest was the increase in the foaming temperature window from 4 degrees C for pristine PP to 8-12 degrees C for the radiation crosslinked PP/HDPE blends. This implies much easier handling of scCO(2) foaming of crosslinked PP with the addition of HDPE.
关键词Radiation cross-linking Polypropylene Supercritical carbon dioxide Microcellular foams Tensile property
收录类别SCI ; EI
语种英语
资助项目National Natural Science Foundation of China[11079048]
WOS研究方向Chemistry ; Nuclear Science & Technology ; Physics
WOS类目Chemistry, Physical ; Nuclear Science & Technology ; Physics, Atomic, Molecular & Chemical
WOS记录号WOS:000412607700043
出版者PERGAMON-ELSEVIER SCIENCE LTD
EI入藏号20173204032259
EI主题词Blowing agents ; Carbon dioxide ; Cells ; Cytology ; Foams ; Gamma rays ; High density polyethylenes ; Polyethylenes ; Supercritical fluid extraction ; Tensile properties ; Tensile strength
EI分类号Biological Materials and Tissue Engineering:461.2 ; Chemical Operations:802.3 ; Chemical Agents and Basic Industrial Chemicals:803 ; Inorganic Compounds:804.2 ; Organic Polymers:815.1.1 ; Atomic and Molecular Physics:931.3 ; Materials Science:951
WOS关键词CARBON-DIOXIDE ; ISOTACTIC POLYPROPYLENE ; CRYSTALLIZATION ; POLYOLEFINS ; IRRADIATION ; PERFORMANCE ; NUCLEATION ; SCAFFOLDS ; HYDROGEN ; LINKING
原始文献类型Article
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文献类型期刊论文
条目标识符https://kms.shanghaitech.edu.cn/handle/2MSLDSTB/9915
专题物质科学与技术学院
物质科学与技术学院_特聘教授组_吴国忠组
物质科学与技术学院_硕士生
通讯作者Wu, Guozhong
作者单位
1.Chinese Acad Sci, Shanghai Inst Appl Phys, Jialuo Rd 2019,POB 800-204, Shanghai 201800, Peoples R China
2.Shanghai Tech Univ, Sch Phys Sci & Technol, Shanghai 200031, Peoples R China
3.Univ China Acad Sci, Beijing 100049, Peoples R China
第一作者单位物质科学与技术学院
通讯作者单位物质科学与技术学院
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GB/T 7714
Yang, Chenguang,Xing, Zhe,Zhang, Mingxing,et al. Supercritical CO2 foaming of radiation crosslinked polypropylene/high-density polyethylene blend: Cell structure and tensile property[J]. RADIATION PHYSICS AND CHEMISTRY,2017,141:276-283.
APA Yang, Chenguang,Xing, Zhe,Zhang, Mingxing,Zhao, Quan,Wang, Mouhua,&Wu, Guozhong.(2017).Supercritical CO2 foaming of radiation crosslinked polypropylene/high-density polyethylene blend: Cell structure and tensile property.RADIATION PHYSICS AND CHEMISTRY,141,276-283.
MLA Yang, Chenguang,et al."Supercritical CO2 foaming of radiation crosslinked polypropylene/high-density polyethylene blend: Cell structure and tensile property".RADIATION PHYSICS AND CHEMISTRY 141(2017):276-283.
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