Palladium-Catalyzed C-H Diarylation of Ferrocenecarboxylic Acids with Aryl Iodides

doi:10.1021/acs.joc.9b01503

	Palladium-Catalyzed C-H Diarylation of Ferrocenecarboxylic Acids with Aryl Iodides
	Xiang, Jia-Chen 1,2; Wu, Zhi-Jie1,3 ; Gu, Qing 1; You, Shu-Li1,3
	2019-10-18
发表期刊	JOURNAL OF ORGANIC CHEMISTRY
ISSN	0022-3263
EISSN	1520-6904
卷号	84 期号:20 页码:13144-13149
发表状态	已发表
DOI	10.1021/acs.joc.9b01503
摘要	Palladium-catalyzed C-H diarylation of ferrocenes is described. In the presence of 10 mol % Pd(OAc)(2), direct C-H diarylation reactions of commercially available ferrocenecarboxylic acid with aryl iodides proceeded smoothly to afford diarylated ferrocenes bearing a variety of functional groups in moderate to good yields. The carboxylic group could also act as a remote directing group to result in the third arylation on the other Cp ring of ferrocene.
收录类别	SCI ; SCIE ; EI ; IC ; CCR
资助项目	Science and Technology Commission of Shanghai Municipality[18JC1411302]
WOS研究方向	Chemistry
WOS类目	Chemistry, Organic
WOS记录号	WOS:000492118100041
出版者	AMER CHEMICAL SOC
EI主题词	Catalysis ; Iron compounds ; Organometallics ; Palladium
WOS关键词	PLANAR CHIRAL FERROCENES ; DIRECT ORTHO-ARYLATION ; ENANTIOSELECTIVE SYNTHESIS ; ASYMMETRIC CATALYSIS ; BENZOIC-ACIDS ; LIGAND ; REDOX ; ACTIVATION ; FUNCTIONALIZATION ; 8-AMINOQUINOLINE
原始文献类型	Article
引用统计
文献类型	期刊论文
条目标识符	https://kms.shanghaitech.edu.cn/handle/2MSLDSTB/80517
专题	物质科学与技术学院_特聘教授组_游书力组物质科学与技术学院_硕士生
共同第一作者	Wu, Zhi-Jie
通讯作者	Gu, Qing; You, Shu-Li
作者单位	1.Chinese Acad Sci, Shanghai Inst Organ Chem, Ctr Excellence Mol Synth, State Key Lab Organometall Chem, 345 Lingling Lu, Shanghai 200032, Peoples R China 2.Cent China Normal Univ, Coll Chem, Minist Educ, Key Lab Pesticide & Chem Biol, Wuhan 430079, Hubei, Peoples R China 3.ShanghaiTech Univ, Sch Phys Sci & Technol, 100 Haike Rd, Shanghai 201210, Peoples R China
通讯作者单位	物质科学与技术学院
推荐引用方式 GB/T 7714	Xiang, Jia-Chen,Wu, Zhi-Jie,Gu, Qing,et al. Palladium-Catalyzed C-H Diarylation of Ferrocenecarboxylic Acids with Aryl Iodides[J]. JOURNAL OF ORGANIC CHEMISTRY,2019,84(20):13144-13149.
APA	Xiang, Jia-Chen,Wu, Zhi-Jie,Gu, Qing,&You, Shu-Li.(2019).Palladium-Catalyzed C-H Diarylation of Ferrocenecarboxylic Acids with Aryl Iodides.JOURNAL OF ORGANIC CHEMISTRY,84(20),13144-13149.
MLA	Xiang, Jia-Chen,et al."Palladium-Catalyzed C-H Diarylation of Ferrocenecarboxylic Acids with Aryl Iodides".JOURNAL OF ORGANIC CHEMISTRY 84.20(2019):13144-13149.