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Catalytic One-Pot Conversion of Renewable Platform Chemicals to Hydrocarbon and Ether Biofuels through Tandem Hf(OTf)(4)+Pd/C Catalysis | |
2019-10-10 | |
发表期刊 | CHEMSUSCHEM (IF:7.5[JCR-2023],8.4[5-Year]) |
ISSN | 1864-5631 |
发表状态 | 已发表 |
DOI | 10.1002/cssc.201902137 |
摘要 | Efficient conversion of renewable biomass platform chemicals into high-quality fuels remains challenging. A one-pot catalytic approach has been developed to synthesize various structurally defined biofuels by using Hf(OTf)(4) and Pd/C for selective tandem catalysis and 2-methylfuran (2-MF) as a renewable feedstock. 2-MF first undergoes Lewis acid-catalyzed hydroxyalkylation/alkylation (HAA) condensation with carbonyl compounds to afford intermediates containing the targeted carbon skeletons of hydrocarbon or ether products, and these intermediates then undergo hydrogenation or hydrodeoxygenation to afford the target products, catalyzed by metal triflate+Pd/C in the same pot. The present process can produce structurally defined alkanes and cyclic ethers under mild conditions. |
关键词 | biomass cyclic ethers hydrocarbons platform chemicals tandem catalyst |
收录类别 | SCI ; SCIE ; EI |
语种 | 英语 |
资助项目 | NSF homogeneous catalysis grant[CHE-1464488] |
WOS研究方向 | Chemistry ; Science & Technology - Other Topics |
WOS类目 | Chemistry, Multidisciplinary ; Green & Sustainable Science & Technology |
WOS记录号 | WOS:000489328700001 |
出版者 | WILEY-V C H VERLAG GMBH |
WOS关键词 | HIGH-QUALITY DIESEL ; DROP-IN BIOFUELS ; SELECTIVE HYDROGENATION ; BIODERIVED FURANS ; LEVULINIC ACID ; RANGE ALKANES ; BIOMASS ; FUELS ; HYDRODEOXYGENATION ; HYDROCRACKING |
原始文献类型 | Article ; Early Access |
引用统计 | 正在获取...
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文献类型 | 期刊论文 |
条目标识符 | https://kms.shanghaitech.edu.cn/handle/2MSLDSTB/80407 |
专题 | 物质科学与技术学院_博士生 物质科学与技术学院_PI研究组_李智组 |
通讯作者 | Li, Zhi |
作者单位 | 1.ShanghaiTech Univ, Sch Phys Sci & Technol, 393 Middle Huaxia Rd, Shanghai 201210, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Northwestern Univ, Dept Chem, 2145 Sheridan Rd, Evanston, IL 60208 USA |
第一作者单位 | 物质科学与技术学院 |
通讯作者单位 | 物质科学与技术学院 |
第一作者的第一单位 | 物质科学与技术学院 |
推荐引用方式 GB/T 7714 | Liu, Dong-Huang,Marks, Tobin J.,Li, Zhi. Catalytic One-Pot Conversion of Renewable Platform Chemicals to Hydrocarbon and Ether Biofuels through Tandem Hf(OTf)(4)+Pd/C Catalysis[J]. CHEMSUSCHEM,2019. |
APA | Liu, Dong-Huang,Marks, Tobin J.,&Li, Zhi.(2019).Catalytic One-Pot Conversion of Renewable Platform Chemicals to Hydrocarbon and Ether Biofuels through Tandem Hf(OTf)(4)+Pd/C Catalysis.CHEMSUSCHEM. |
MLA | Liu, Dong-Huang,et al."Catalytic One-Pot Conversion of Renewable Platform Chemicals to Hydrocarbon and Ether Biofuels through Tandem Hf(OTf)(4)+Pd/C Catalysis".CHEMSUSCHEM (2019). |
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