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ShanghaiTech University Knowledge Management System
An Allosteric Metal-Organic Framework That Exhibits Multiple Pore Configurations for the Optimization of Hydrocarbon Separation | |
2019-10-15 | |
发表期刊 | CHEMISTRY-AN ASIAN JOURNAL (IF:3.5[JCR-2023],3.9[5-Year]) |
ISSN | 1861-4728 |
卷号 | 14期号:20页码:3552-3556 |
发表状态 | 已发表 |
DOI | 10.1002/asia.201900239 |
摘要 | The function of allosteric enzymes can be activated or inhibited through binding of specific effector molecules. Herein, we describe how the skeletal deformation, pore configuration, and ultimately adsorptive behavior of a dynamic metal-organic framework (MOF), (Me2NH2)[In(atp)](2) (in which atp=2-aminoterephthalate), are controlled by the allocation and orientation of its counter ions triggered by the inclusion/removal of different guest molecules. The power of such allosteric control in MOFs is highlighted through the optimization of the hydrocarbon separation performance by achieving multiple pore configurations but without altering the chemical composition. |
关键词 | adsorption gas separation metal-organic frameworks porous materials solvent effects |
收录类别 | SCI ; SCIE ; EI |
语种 | 英语 |
资助项目 | National Outstanding Youth Foundation of China[21522105] |
WOS研究方向 | Chemistry |
WOS类目 | Chemistry, Multidisciplinary |
WOS记录号 | WOS:000490021100008 |
出版者 | WILEY-V C H VERLAG GMBH |
WOS关键词 | ADSORPTION ; METHANE ; SORPTION ; CO2 |
原始文献类型 | Article |
引用统计 | 正在获取...
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文献类型 | 期刊论文 |
条目标识符 | https://kms.shanghaitech.edu.cn/handle/2MSLDSTB/80390 |
专题 | 物质科学与技术学院_硕士生 物质科学与技术学院_PI研究组_章跃标组 物质科学与技术学院_博士生 |
通讯作者 | Zhang, Yue-Biao |
作者单位 | 1.ShanghaiTech Univ, Sch Phys Sci & Technol, Shanghai 201210, Peoples R China 2.Kyoto Univ, Inst Adv Study, Inst Integrated Cell Mat Sci, Kyoto 6068501, Japan 3.Chinese Acad Sci, Shanghai Inst Ceram, Shanghai 200050, Peoples R China 4.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
第一作者单位 | 物质科学与技术学院 |
通讯作者单位 | 物质科学与技术学院 |
第一作者的第一单位 | 物质科学与技术学院 |
推荐引用方式 GB/T 7714 | Zhou, Beibei,Zeng, Tengwu,Shi, Zhao-Lin,et al. An Allosteric Metal-Organic Framework That Exhibits Multiple Pore Configurations for the Optimization of Hydrocarbon Separation[J]. CHEMISTRY-AN ASIAN JOURNAL,2019,14(20):3552-3556. |
APA | Zhou, Beibei,Zeng, Tengwu,Shi, Zhao-Lin,Zhang, Gen,Horike, Satoshi,&Zhang, Yue-Biao.(2019).An Allosteric Metal-Organic Framework That Exhibits Multiple Pore Configurations for the Optimization of Hydrocarbon Separation.CHEMISTRY-AN ASIAN JOURNAL,14(20),3552-3556. |
MLA | Zhou, Beibei,et al."An Allosteric Metal-Organic Framework That Exhibits Multiple Pore Configurations for the Optimization of Hydrocarbon Separation".CHEMISTRY-AN ASIAN JOURNAL 14.20(2019):3552-3556. |
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