An Allosteric Metal-Organic Framework That Exhibits Multiple Pore Configurations for the Optimization of Hydrocarbon Separation

doi:10.1002/asia.201900239

	An Allosteric Metal-Organic Framework That Exhibits Multiple Pore Configurations for the Optimization of Hydrocarbon Separation
	Zhou, Beibei1,3,4 ; Zeng, Tengwu1 ; Shi, Zhao-Lin1 ; Zhang, Gen 2; Horike, Satoshi 2; Zhang, Yue-Biao1
	2019-10-15
发表期刊	CHEMISTRY-AN ASIAN JOURNAL (IF:3.5[JCR-2023],3.9[5-Year])
ISSN	1861-4728
卷号	14 期号:20 页码:3552-3556
发表状态	已发表
DOI	10.1002/asia.201900239
摘要	The function of allosteric enzymes can be activated or inhibited through binding of specific effector molecules. Herein, we describe how the skeletal deformation, pore configuration, and ultimately adsorptive behavior of a dynamic metal-organic framework (MOF), (Me2NH2)[In(atp)](2) (in which atp=2-aminoterephthalate), are controlled by the allocation and orientation of its counter ions triggered by the inclusion/removal of different guest molecules. The power of such allosteric control in MOFs is highlighted through the optimization of the hydrocarbon separation performance by achieving multiple pore configurations but without altering the chemical composition.
关键词	adsorption gas separation metal-organic frameworks porous materials solvent effects
收录类别	SCI ; SCIE ; EI
语种	英语
资助项目	National Outstanding Youth Foundation of China[21522105]
WOS研究方向	Chemistry
WOS类目	Chemistry, Multidisciplinary
WOS记录号	WOS:000490021100008
出版者	WILEY-V C H VERLAG GMBH
WOS关键词	ADSORPTION ; METHANE ; SORPTION ; CO2
原始文献类型	Article
引用统计	正在获取...
文献类型	期刊论文
条目标识符	https://kms.shanghaitech.edu.cn/handle/2MSLDSTB/80390
专题	物质科学与技术学院_硕士生物质科学与技术学院_PI研究组_章跃标组物质科学与技术学院_博士生
通讯作者	Zhang, Yue-Biao
作者单位	1.ShanghaiTech Univ, Sch Phys Sci & Technol, Shanghai 201210, Peoples R China 2.Kyoto Univ, Inst Adv Study, Inst Integrated Cell Mat Sci, Kyoto 6068501, Japan 3.Chinese Acad Sci, Shanghai Inst Ceram, Shanghai 200050, Peoples R China 4.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
第一作者单位	物质科学与技术学院
通讯作者单位	物质科学与技术学院
第一作者的第一单位	物质科学与技术学院
推荐引用方式 GB/T 7714	Zhou, Beibei,Zeng, Tengwu,Shi, Zhao-Lin,et al. An Allosteric Metal-Organic Framework That Exhibits Multiple Pore Configurations for the Optimization of Hydrocarbon Separation[J]. CHEMISTRY-AN ASIAN JOURNAL,2019,14(20):3552-3556.
APA	Zhou, Beibei,Zeng, Tengwu,Shi, Zhao-Lin,Zhang, Gen,Horike, Satoshi,&Zhang, Yue-Biao.(2019).An Allosteric Metal-Organic Framework That Exhibits Multiple Pore Configurations for the Optimization of Hydrocarbon Separation.CHEMISTRY-AN ASIAN JOURNAL,14(20),3552-3556.
MLA	Zhou, Beibei,et al."An Allosteric Metal-Organic Framework That Exhibits Multiple Pore Configurations for the Optimization of Hydrocarbon Separation".CHEMISTRY-AN ASIAN JOURNAL 14.20(2019):3552-3556.