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An Allosteric Metal-Organic Framework That Exhibits Multiple Pore Configurations for the Optimization of Hydrocarbon Separation
2019-10-15
发表期刊CHEMISTRY-AN ASIAN JOURNAL (IF:3.5[JCR-2023],3.9[5-Year])
ISSN1861-4728
卷号14期号:20页码:3552-3556
发表状态已发表
DOI10.1002/asia.201900239
摘要The function of allosteric enzymes can be activated or inhibited through binding of specific effector molecules. Herein, we describe how the skeletal deformation, pore configuration, and ultimately adsorptive behavior of a dynamic metal-organic framework (MOF), (Me2NH2)[In(atp)](2) (in which atp=2-aminoterephthalate), are controlled by the allocation and orientation of its counter ions triggered by the inclusion/removal of different guest molecules. The power of such allosteric control in MOFs is highlighted through the optimization of the hydrocarbon separation performance by achieving multiple pore configurations but without altering the chemical composition.
关键词adsorption gas separation metal-organic frameworks porous materials solvent effects
收录类别SCI ; SCIE ; EI
语种英语
资助项目National Outstanding Youth Foundation of China[21522105]
WOS研究方向Chemistry
WOS类目Chemistry, Multidisciplinary
WOS记录号WOS:000490021100008
出版者WILEY-V C H VERLAG GMBH
WOS关键词ADSORPTION ; METHANE ; SORPTION ; CO2
原始文献类型Article
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文献类型期刊论文
条目标识符https://kms.shanghaitech.edu.cn/handle/2MSLDSTB/80390
专题物质科学与技术学院_硕士生
物质科学与技术学院_PI研究组_章跃标组
物质科学与技术学院_博士生
通讯作者Zhang, Yue-Biao
作者单位
1.ShanghaiTech Univ, Sch Phys Sci & Technol, Shanghai 201210, Peoples R China
2.Kyoto Univ, Inst Adv Study, Inst Integrated Cell Mat Sci, Kyoto 6068501, Japan
3.Chinese Acad Sci, Shanghai Inst Ceram, Shanghai 200050, Peoples R China
4.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
第一作者单位物质科学与技术学院
通讯作者单位物质科学与技术学院
第一作者的第一单位物质科学与技术学院
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GB/T 7714
Zhou, Beibei,Zeng, Tengwu,Shi, Zhao-Lin,et al. An Allosteric Metal-Organic Framework That Exhibits Multiple Pore Configurations for the Optimization of Hydrocarbon Separation[J]. CHEMISTRY-AN ASIAN JOURNAL,2019,14(20):3552-3556.
APA Zhou, Beibei,Zeng, Tengwu,Shi, Zhao-Lin,Zhang, Gen,Horike, Satoshi,&Zhang, Yue-Biao.(2019).An Allosteric Metal-Organic Framework That Exhibits Multiple Pore Configurations for the Optimization of Hydrocarbon Separation.CHEMISTRY-AN ASIAN JOURNAL,14(20),3552-3556.
MLA Zhou, Beibei,et al."An Allosteric Metal-Organic Framework That Exhibits Multiple Pore Configurations for the Optimization of Hydrocarbon Separation".CHEMISTRY-AN ASIAN JOURNAL 14.20(2019):3552-3556.
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