Investigation of mesoporous NiAl2O4/MOx (M = La, Ce, Ca, Mg)-gamma-Al2O3 nanocomposites for dry reforming of methane

doi:10.1039/c7ra04497f

	Investigation of mesoporous NiAl2O4/MOx (M = La, Ce, Ca, Mg)-gamma-Al2O3 nanocomposites for dry reforming of methane
	Zhang, Li; Wang, Xueguang; Chen, Chenju; Zou, Xiujing; Shang, Xingfu; Ding, Weizhong; Lu, Xionggang
	2017
发表期刊	RSC ADVANCES
ISSN	2046-2069
卷号	7 期号:53 页码:33143-33154
发表状态	已发表
DOI	10.1039/c7ra04497f
摘要	One- pot synthesized mesoporous NiAl2O4/gamma-Al2O3 and NiAl2O4/MOx (M = La, Ce, Ca, Mg)-gamma-Al2O3 nanocomposites with excellent textural properties were employed for the dry reforming of methane (DRM). NiAl2O4/La2O3/gamma-Al2O3-imp prepared via a traditional impregnation method was used for comparison. The promotion effect of modifiers on the physicochemical properties and catalytic performance of the catalysts was systematically investigated. Characterization and evaluation results indicated that the modified catalysts showed higher activities and better coking-resistance than Ni/gamma-Al2O3, and Ni/La2O3-gamma-Al2O3 was found to be the most effective one. All the catalysts with or without modifiers presented similar Ni particle sizes due to the enhanced metal-support interaction derived from the reduction of the NiAl2O4 precursor. However, more medium-strength basic sites on the catalyst surface were obtained by adding promoters, which could facilitate the adsorption/activation of CO2 and the gasification of amorphous carbon, improving the catalytic properties and accelerating the coke elimination rate. Additionally, the incorporation of promoters also prevented the phase transformation of gamma-alumina.
收录类别	SCI
语种	英语
WOS研究方向	Chemistry
WOS类目	Chemistry, Multidisciplinary
WOS记录号	WOS:000404864100012
出版者	ROYAL SOC CHEMISTRY
引用统计
文献类型	期刊论文
条目标识符	https://kms.shanghaitech.edu.cn/handle/2MSLDSTB/6223
专题	个人在本单位外知识产出
作者单位	[Zhang, Li; Wang, Xueguang; Chen, Chenju; Ding, Weizhong; Lu, Xionggang] Shanghai Univ, State Key Lab Adv Special Steel, Shanghai 200072, Peoples R China; [Wang, Xueguang; Zou, Xiujing; Shang, Xingfu; Ding, Weizhong] Shanghai Univ, Shanghai Key Lab Adv Ferromet, Shanghai, Peoples R China
推荐引用方式 GB/T 7714	Zhang, Li,Wang, Xueguang,Chen, Chenju,et al. Investigation of mesoporous NiAl2O4/MOx (M = La, Ce, Ca, Mg)-gamma-Al2O3 nanocomposites for dry reforming of methane[J]. RSC ADVANCES,2017,7(53):33143-33154.
APA	Zhang, Li.,Wang, Xueguang.,Chen, Chenju.,Zou, Xiujing.,Shang, Xingfu.,...&Lu, Xionggang.(2017).Investigation of mesoporous NiAl2O4/MOx (M = La, Ce, Ca, Mg)-gamma-Al2O3 nanocomposites for dry reforming of methane.RSC ADVANCES,7(53),33143-33154.
MLA	Zhang, Li,et al."Investigation of mesoporous NiAl2O4/MOx (M = La, Ce, Ca, Mg)-gamma-Al2O3 nanocomposites for dry reforming of methane".RSC ADVANCES 7.53(2017):33143-33154.