Synthesis and Electrochemical Study of Bipolar Molecules Containing Dihydrophenazine and Anthraquinone Moieties

doi:10.6023/cjoc202407011

	Synthesis and Electrochemical Study of Bipolar Molecules Containing Dihydrophenazine and Anthraquinone Moieties
	Li, Jianfa1,2 ; Duan, An 1; Huang, Xiaoyu1,2 ; Li, Yongjun 1
	2025
发表期刊	CHINESE JOURNAL OF ORGANIC CHEMISTRY (IF:1.8[JCR-2023],1.3[5-Year])
ISSN	0253-2786
卷号	45 期号:1 页码:319-324
发表状态	已发表
DOI	10.6023/cjoc202407011
摘要	Design and synthesis of electrochemical active molecules with high specific capacity attracted much research attention in the field of organic electrode materials for rechargeable betteries. Two bipolar molecules BPZ-AQ and 2BPZ-AQ which were composed of p-type dihydrophenazine and n-type anthraquinone moieties were synthesized via Buchwald-Hartwig coupling reaction. BPZ-AQ and 2BPZ-AQ could deliver high specific capacity of 230 and 223 mAh center dot g(-1), respectively. Their bipolar-type property was investigated by absorption spectrum and cyclic voltammetry characterization, confirming the electrochemical activity of dihydrophenazine and anthraquinone moieties in the bipolar molecules. 2BPZ-AQ can present a high initial capacity of 210 mAh center dot g(-1) at 1 C corresponding to 94% of its theoretical capacity, good capacity retention (60%) after 200 cycles, and excellent rate performance.
关键词	双极型分子蒽醌二氢吩嗪有机正极材料
URL	查看原文
收录类别	SCI ; 中国科技核心期刊 ; CSCD ; 北大核心
语种	中文
资助项目	National Natural Science Foundation of China["52273086","U22A20131"] ; Shanghai Scientific and Technological Innova-tion Project[22520711700]
WOS研究方向	Chemistry
WOS类目	Chemistry, Organic
WOS记录号	WOS:001438637800010
出版者	SCIENCE PRESS
原始文献类型	Periodical
来源库	WanFang
文献类型	期刊论文
条目标识符	https://kms.shanghaitech.edu.cn/handle/2MSLDSTB/401461
专题	物质科学与技术学院物质科学与技术学院_特聘教授组_黄晓宇组物质科学与技术学院_硕士生
通讯作者	Huang, Xiaoyu; Li, Yongjun
作者单位	1.Chinese Acad Sci, Shanghai Inst Organ Chem, Shanghai 200032, Peoples R China 2.ShanghaiTech Univ, Sch Phys Sci & Technol, Shanghai 201210, Peoples R China
第一作者单位	物质科学与技术学院
通讯作者单位	物质科学与技术学院
推荐引用方式 GB/T 7714	Li, Jianfa,Duan, An,Huang, Xiaoyu,et al. Synthesis and Electrochemical Study of Bipolar Molecules Containing Dihydrophenazine and Anthraquinone Moieties[J]. CHINESE JOURNAL OF ORGANIC CHEMISTRY,2025,45(1):319-324.
APA	Li, Jianfa,Duan, An,Huang, Xiaoyu,&Li, Yongjun.(2025).Synthesis and Electrochemical Study of Bipolar Molecules Containing Dihydrophenazine and Anthraquinone Moieties.CHINESE JOURNAL OF ORGANIC CHEMISTRY,45(1),319-324.
MLA	Li, Jianfa,et al."Synthesis and Electrochemical Study of Bipolar Molecules Containing Dihydrophenazine and Anthraquinone Moieties".CHINESE JOURNAL OF ORGANIC CHEMISTRY 45.1(2025):319-324.