上海科技大学知识管理系统

Foamed concrete is a kind of lightweight insulation material formed by the uniform mixture of foam and cement slurry. The superhydrophobic bulk modification of foamed concrete can reduce its high water absorption and prolong its service life. In this paper, the compatibility of three hydrophobic agents named polydimethylsiloxane (PDMS), isoctyltriethoxysilane (ICTS) and SBT®-TIA with foams was studied, and the reasons of incompatibility were revealed. Then, the superhydrophobic bulk foamed concrete system was constructed by physical foaming method, adding polydimethylsiloxane (PDMS), calcium stearate (CS), nano-silica (NS) and covering the surface of the specimen with 200-mesh wire mesh. The results show that the maximum contact angles of the meshed surface and the internal polished surface of superhydrophobic foamed concrete were 162.7° and 153.5°, respectively. At the same time, the water absorption rate of the modified specimen was significantly reduced, and the reduction rate was up to 90 %. In addition, the deterioration degree of thermal insulation performance after soaking and the dry shrinkage rate were significantly reduced compared with ordinary foamed concrete. Scanning electron microscopy (SEM) revealed that increasing the multi-scale roughness could improve the hydrophobic properties of foamed concrete. Fourier infrared spectroscopy (FT-IR) also confirmed that low surface energy groups such as -CH2 and -CH3 in PDMS bonded to the cement hydration products, indicating the successful preparation of superhydrophobic bulk foamed concrete. © 2024 Elsevier Ltd