Photoredox-catalyzed hydrogenation of alkenes assisted by an <i>in situ</i> generated PPh<sub>3</sub>(OH) radical and acetic acid

doi:10.1039/d4qo00661e

	*Photoredox-catalyzed hydrogenation of alkenes assisted by an in situ* generated PPh₃(OH) radical and acetic acid**
	Xie, Zhen-Zhen 1; Zheng, Yu1,2 ; Liao, Zi-Hao 1; Yuan, Chu-Ping 1; Li, Ming-Zhi 1; Deng, Ke-Yi 1; Xiang, Hao-Yue 1; Chen, Kai 1; Yang, Hua 1
	2024-06-01
发表期刊	ORGANIC CHEMISTRY FRONTIERS (IF:4.6[JCR-2023],4.3[5-Year])
ISSN	2052-4129
EISSN	2052-4129
卷号	11 期号:15 页码:4187-4193
发表状态	已发表
DOI	10.1039/d4qo00661e
摘要	Herein, a practical, mild and convenient strategy was disclosed for the hydrogenation of alkenes under photocatalytic conditions through a HAT/protonation process. A combination of experimental and computational studies suggested that water was activated by a phosphine radical cation to generate the critical intermediate, the PR3(OH) radical, which acted as a "free" hydrogen atom to facilitate the initial HAT process.
关键词	Atoms Olefins Phosphorus compounds Computational studies Condition Hydrogen atoms OH radical Photo-catalytic Protonations Radical cations
URL	查看原文
收录类别	SCI ; EI
语种	英语
资助项目	National Natural Science Foundation of China[
WOS研究方向	Chemistry
WOS类目	Chemistry, Organic
WOS记录号	WOS:001246441500001
出版者	ROYAL SOC CHEMISTRY
EI入藏号	20242516275019
EI主题词	Hydrogenation
EI分类号	802.2 Chemical Reactions ; 804.1 Organic Compounds ; 931.3 Atomic and Molecular Physics
原始文献类型	Article in Press
引用统计	正在获取...
文献类型	期刊论文
条目标识符	https://kms.shanghaitech.edu.cn/handle/2MSLDSTB/395910
专题	物质科学与技术学院物质科学与技术学院_PI研究组_黄焕明组
通讯作者	Chen, Kai; Yang, Hua
作者单位	1.Cent South Univ, Coll Chem & Chem Engn, Changsha 410083, Peoples R China 2.ShanghaiTech Univ, Sch Phys Sci & Technol, Shanghai 201210, Peoples R China
推荐引用方式 GB/T 7714	Xie, Zhen-Zhen,Zheng, Yu,Liao, Zi-Hao,et al. Photoredox-catalyzed hydrogenation of alkenes assisted by an in situ generated PPh₃(OH) radical and acetic acid[J]. ORGANIC CHEMISTRY FRONTIERS,2024,11(15):4187-4193.
APA	Xie, Zhen-Zhen.,Zheng, Yu.,Liao, Zi-Hao.,Yuan, Chu-Ping.,Li, Ming-Zhi.,...&Yang, Hua.(2024).Photoredox-catalyzed hydrogenation of alkenes assisted by an in situ generated PPh₃(OH) radical and acetic acid.ORGANIC CHEMISTRY FRONTIERS,11(15),4187-4193.
MLA	Xie, Zhen-Zhen,et al."Photoredox-catalyzed hydrogenation of alkenes assisted by an in situ generated PPh₃(OH) radical and acetic acid".ORGANIC CHEMISTRY FRONTIERS 11.15(2024):4187-4193.