Strong Metal-Support Interactions: From Characterization, Manipulation to Application in Fischer-Tropsch Synthesis and Atmospheric CO2 hydrogenation

doi:10.1002/cctc.202301623

	Strong Metal-Support Interactions: From Characterization, Manipulation to Application in Fischer-Tropsch Synthesis and Atmospheric CO2 hydrogenation
	Zhang, Wenzhe1,2 ; Lin, Heyun 1; An, Yunlei 1; Lin, Tiejun 2,3; Zhong, Liangshu1,2,3
	2024
发表期刊	CHEMCATCHEM (IF:3.8[JCR-2023],4.6[5-Year])
ISSN	1867-3880
EISSN	1867-3899
卷号	16 期号:15
发表状态	已发表
DOI	10.1002/cctc.202301623
摘要	Strong metal-support interactions (SMSI) featuring the formation of encapsulation overlayer around metal nanoparticles has drawn much attention in heterogeneous catalysis. Recent years, various novel SMSI phenomena have been observed and the nature of SMSI also has been revealed with the improvement of characterization techniques. Understanding the SMSI effect could deepen the insight into the structure-activity relationship of metal-supported catalysts, and rationally guide the design of special metal-interface sites to manipulate catalytic behavior in chemical reaction. In this review, the research progress of SMSI and its application in heterogeneous COx hydrogenation are briefly surveyed, with emphasis on the advanced characterization, manipulation strategy and specific role of SMSI in Fischer-Tropsch synthesis process, CO2 methanation and Reverse Water Gas Shift reaction. The current challenges and perspectives for the development of SMSI are also discussed. © 2024 Wiley-VCH GmbH.
关键词	Carbon dioxide Chemical shift Fischer-Tropsch synthesis Metal nanoparticles Water gas shift Atmospheric CO 2 Characterization techniques COx hydrogenation Interaction effect Interaction phenomena Metal-support interactions Overlayers Strong metal-support interaction Structural sensitivity Structure-activity relationships
收录类别	EI
语种	英语
出版者	John Wiley and Sons Inc
EI入藏号	20240715540818
EI主题词	Hydrogenation
EI分类号	761 Nanotechnology ; 802.2 Chemical Reactions ; 804.2 Inorganic Compounds ; 931.3 Atomic and Molecular Physics
原始文献类型	Article in Press
引用统计	正在获取...
文献类型	期刊论文
条目标识符	https://kms.shanghaitech.edu.cn/handle/2MSLDSTB/349746
专题	物质科学与技术学院物质科学与技术学院_特聘教授组_钟良枢组物质科学与技术学院_硕士生
通讯作者	Lin, Tiejun; Zhong, Liangshu
作者单位	1.Key Laboratory of Low-Carbon Conversion Science and Engineering, Shanghai Advanced Research Institute, Chinese Academy of Sciences, Shanghai; 201210, China 2.School of Physical Science and Technology, ShanghaiTech University, Shanghai; 201210, China 3.University of the Chinese Academy of Sciences, Beijing; 100049, China
第一作者单位	物质科学与技术学院
通讯作者单位	物质科学与技术学院
推荐引用方式 GB/T 7714	Zhang, Wenzhe,Lin, Heyun,An, Yunlei,et al. Strong Metal-Support Interactions: From Characterization, Manipulation to Application in Fischer-Tropsch Synthesis and Atmospheric CO2 hydrogenation[J]. CHEMCATCHEM,2024,16(15).
APA	Zhang, Wenzhe,Lin, Heyun,An, Yunlei,Lin, Tiejun,&Zhong, Liangshu.(2024).Strong Metal-Support Interactions: From Characterization, Manipulation to Application in Fischer-Tropsch Synthesis and Atmospheric CO2 hydrogenation.CHEMCATCHEM,16(15).
MLA	Zhang, Wenzhe,et al."Strong Metal-Support Interactions: From Characterization, Manipulation to Application in Fischer-Tropsch Synthesis and Atmospheric CO2 hydrogenation".CHEMCATCHEM 16.15(2024).