Integrated Anionic Zirconium-Organic Cage and Cationic Boron-Imidazolate Cage for Synergetic Optical Limiting

doi:10.1002/anie.202318806

	Integrated Anionic Zirconium-Organic Cage and Cationic Boron-Imidazolate Cage for Synergetic Optical Limiting
	Li, Yi-Fei1,2 ; He, Yan-Ping 1; Li, Qiao-Hong 1; Zhang, Jian 1
	2024
发表期刊	ANGEWANDTE CHEMIE - INTERNATIONAL EDITION (IF:16.1[JCR-2023],16.2[5-Year])
ISSN	1433-7851
EISSN	1521-3773
卷号	63 期号:12
发表状态	已发表
DOI	10.1002/anie.202318806
摘要	Making oppositely charged metal-organic cages (MOCs) into a tightly ordered structure may bring interesting functions. Herein, we report a novel structure composed of anionic (Zr4L6)8− (L=embonate) tetrahedral cages and in situ-formed cationic [Zn4(Bim)4]4+ (Bim=[BH(im)3]−; im=imidazole) cubic cages. Chiral transfer is observed from enantiopure (Zr4L6)8− cage to enantiopure [Zn4(Bim)4]4+ cage. A pair of enantiomers (PTC-373(Δ) and PTC-373(Λ)) are formed. PTC-373 exhibits high chemical and thermal stabilities, affording an interesting single-crystal-to-single-crystal transformation. More importantly, the combination of ionic pair cages significantly enhances its third-order nonlinear optical property, and its thin-film exhibits an excellent optical limiting effect. © 2024 Wiley-VCH GmbH.
关键词	Boron Optical properties Organometallics Single crystals Stereochemistry Zirconium Boron-imidazolate cage Cationics Co-operative assembly Enantiopure Imidazolate Metalorganics Optical limiting Organics Synergetics Zirconium-organic cage
收录类别	SCI ; EI
语种	英语
出版者	John Wiley and Sons Inc
EI入藏号	20240715549701
EI主题词	Nonlinear optics
EI分类号	549.3 Nonferrous Metals and Alloys excluding Alkali and Alkaline Earth Metals ; 741.1 Light/Optics ; 741.1.1 Nonlinear Optics ; 801 Chemistry ; 804.1 Organic Compounds ; 933.1 Crystalline Solids
原始文献类型	Article in Press
引用统计	正在获取...
文献类型	期刊论文
条目标识符	https://kms.shanghaitech.edu.cn/handle/2MSLDSTB/349743
专题	物质科学与技术学院物质科学与技术学院_硕士生
通讯作者	He, Yan-Ping; Zhang, Jian
作者单位	1.State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou; Fujian 350002, China 2.School of Physical Science and Technology, ShanghaiTech University, Shanghai; 201210, China
第一作者单位	物质科学与技术学院
推荐引用方式 GB/T 7714	Li, Yi-Fei,He, Yan-Ping,Li, Qiao-Hong,et al. Integrated Anionic Zirconium-Organic Cage and Cationic Boron-Imidazolate Cage for Synergetic Optical Limiting[J]. ANGEWANDTE CHEMIE - INTERNATIONAL EDITION,2024,63(12).
APA	Li, Yi-Fei,He, Yan-Ping,Li, Qiao-Hong,&Zhang, Jian.(2024).Integrated Anionic Zirconium-Organic Cage and Cationic Boron-Imidazolate Cage for Synergetic Optical Limiting.ANGEWANDTE CHEMIE - INTERNATIONAL EDITION,63(12).
MLA	Li, Yi-Fei,et al."Integrated Anionic Zirconium-Organic Cage and Cationic Boron-Imidazolate Cage for Synergetic Optical Limiting".ANGEWANDTE CHEMIE - INTERNATIONAL EDITION 63.12(2024).