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High thermal stability and optical contrast of Mo-doped Ge8Sb2Te11 films prepared by magnetron co-sputtering
2023-11-15
发表期刊CERAMICS INTERNATIONAL (IF:5.1[JCR-2023],4.7[5-Year])
ISSN0272-8842
卷号49期号:24页码:40105-40111
发表状态已发表
DOI10.1016/j.ceramint.2023.09.341
摘要

In this work, Ge8Sb2Te11 (GST) films with high melting point element Mo doping were prepared by magnetron co-sputtering, and the influence of Mo content on the phase transformation and optical properties of the films was investigated. The results of GIXRD, XPS, and ellipsometry analysis show that Mo will occupy the lattice vacancy, promoting grain growth and accelerating phase transitions. With an increase in Mo content, the phase transition temperature of the films can reach 360 °C, and the amorphous thermal stability of the films can be enhanced by Mo doping. Meanwhile, the optical properties of the films are improved. The optical band gap of Mo-doped films is reduced, the absorption coefficient rises, and the refractive index contrast of GST films with low Mo-doping in the Vis-NIR band is as high as 2.27. This result will make it possible to apply Ge8Sb2Te11 thin films in structural color fields and broaden their color spectrum.

关键词Ge8Sb2Te11 Mo contents Thermal properties Refractive index contrast Magnetron co-sputtering
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收录类别SCI ; EI
语种英语
出版者Elsevier Ltd
EI入藏号20234014837067
EI主题词Thin films
EI分类号543.3 Molybdenum and Alloys ; 641.1 Thermodynamics ; 712.1 Semiconducting Materials ; 714.1 Electron Tubes ; 741.1 Light/Optics ; 933.1.2 Crystal Growth
原始文献类型Journal article (JA)
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文献类型期刊论文
条目标识符https://kms.shanghaitech.edu.cn/handle/2MSLDSTB/345945
专题物质科学与技术学院_硕士生
通讯作者Yuzhi, Zhang; Lixin, Song
作者单位
1.Key Laboratory of Inorganic Coatings Materials CAS, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai, 200050, PR China
2.Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing, 100049, PR China
3.School of Physical Science and Technology, ShanghaiTech University, Shanghai, 201210, PR China
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GB/T 7714
Yan, Zhang,Yuzhi, Zhang,Rumeng, Song,et al. High thermal stability and optical contrast of Mo-doped Ge8Sb2Te11 films prepared by magnetron co-sputtering[J]. CERAMICS INTERNATIONAL,2023,49(24):40105-40111.
APA Yan, Zhang,Yuzhi, Zhang,Rumeng, Song,Jiayu, Ma,Lingnan, Wu,&Lixin, Song.(2023).High thermal stability and optical contrast of Mo-doped Ge8Sb2Te11 films prepared by magnetron co-sputtering.CERAMICS INTERNATIONAL,49(24),40105-40111.
MLA Yan, Zhang,et al."High thermal stability and optical contrast of Mo-doped Ge8Sb2Te11 films prepared by magnetron co-sputtering".CERAMICS INTERNATIONAL 49.24(2023):40105-40111.
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