Textured Sr2Sc0.1Nb0.1Co1.5Fe0.3O6-2 Thin Film Cathodes for IT-SOFCs
2019-03
发表期刊MATERIALS
ISSN1996-1944
卷号12期号:5
发表状态已发表
DOI10.3390/ma12050777
摘要Reducing the operating temperature of solid oxide fuel cells (SOFCs) to intermediate (650-850 degrees C) or even lower levels (400-650 degrees C) is an important practical requirement. However, the main obstacle to lowering the operating temperature is the poor oxygen reduction reaction (ORR) activity on the cathode side and, therefore, it is essential to explore cathode materials with good ORR activity in these temperature ranges. In this work, we investigated the possibility of using Sr2Sc0.1Nb0.1Co1.5Fe0.3O6-2 (SSNCF) as a suitable intermediate temperature cathode material. SSNCF thin films with different orientations were prepared using the pulsed laser deposition technique, and the relationship of the surface chemical states and ORR activity was discussed in terms of crystallographic orientation. The results showed that the SSNCF/YSZ grown along the [110] direction exhibited superior ORR activity compared to the SSNCF/SDC/YSZ thin film electrode grown along the [100] direction. This was explained by the variation in the Sr-surface enrichment and cobalt ion oxidation state using X-ray photoemission spectroscopy.
关键词SOFCs mixed ionic electronic conductor ORR thin films surface chemistry
收录类别SCI ; SCIE ; EI
语种英语
资助项目Jiangsu Natural Science Foundation for Distinguished Young Scholars[BK20170043]
WOS研究方向Materials Science
WOS类目Materials Science, Multidisciplinary
WOS记录号WOS:000462543700093
出版者MDPI
EI入藏号20192507072436
EI主题词Cathodes ; Electrolytic reduction ; Fuel cells ; Iron compounds ; Niobium compounds ; Photoelectron spectroscopy ; Pulsed laser deposition ; Strontium compounds ; Surface chemistry ; Temperature ; Textures ; Thin films
EI分类号Ore Treatment:533.1 ; Thermodynamics:641.1 ; Fuel Cells:702.2 ; Laser Applications:744.9 ; Physical Chemistry:801.4
WOS关键词X-RAY PHOTOELECTRON ; OXIDE FUEL-CELLS ; SURFACE ; PERFORMANCE ; SRNB0.1CO0.9O3-DELTA
原始文献类型Article
引用统计
文献类型期刊论文
条目标识符https://kms.shanghaitech.edu.cn/handle/2MSLDSTB/34191
专题物质科学与技术学院_硕士生
物质科学与技术学院_PI研究组_杨楠组
通讯作者Zhou, Wei; Yang, Nan
作者单位
1.ShanghaiTech Univ, Sch Phys Sci & Technol, 393 Middle Huaxia Rd, Shanghai 201210, Peoples R China
2.Chinese Acad Sci, Shanghai Inst Ceram, Shanghai 200050, Peoples R China
3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
4.Nanjing Tech Univ, Jiangsu Natl Synerget Innovat Ctr Adv Mat SICAM, State Key Lab Mat Oriented Chem Engn, Coll Chem Engn, 5 Xin Mofan Rd, Nanjing 210009, Jiangsu, Peoples R China
第一作者单位物质科学与技术学院
通讯作者单位物质科学与技术学院
第一作者的第一单位物质科学与技术学院
推荐引用方式
GB/T 7714
Zhu, Zhaoxin,Zhou, Chuan,Zhou, Wei,et al. Textured Sr2Sc0.1Nb0.1Co1.5Fe0.3O6-2 Thin Film Cathodes for IT-SOFCs[J]. MATERIALS,2019,12(5).
APA Zhu, Zhaoxin,Zhou, Chuan,Zhou, Wei,&Yang, Nan.(2019).Textured Sr2Sc0.1Nb0.1Co1.5Fe0.3O6-2 Thin Film Cathodes for IT-SOFCs.MATERIALS,12(5).
MLA Zhu, Zhaoxin,et al."Textured Sr2Sc0.1Nb0.1Co1.5Fe0.3O6-2 Thin Film Cathodes for IT-SOFCs".MATERIALS 12.5(2019).
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