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| Type-II Red Phosphorus: Wavy Packing of Twisted Pentagonal Tubes | |
| 2023 | |
| Source Publication | ANGEWANDTE CHEMIE - INTERNATIONAL EDITION
 |
| ISSN | 1433-7851 |
| EISSN | 1521-3773 |
| Volume | 62Issue:36 |
| Status | 已发表 |
| DOI | 10.1002/anie.202307102 |
| Abstract | Elemental phosphorus exhibits fascinating structural varieties and versatile properties. The unique nature of phosphorus bonds can lead to the formation of extremely complex structures, and detailed structural information on some phosphorus polymorphs is yet to be investigated. In this study, we investigated an unidentified crystalline phase of phosphorus, type-II red phosphorus (RP), by combining state-of-the-art structural characterization techniques. Electron diffraction tomography, atomic-resolution scanning transmission electron microscopy (STEM), powder X-ray diffraction, and Raman spectroscopy were concurrently used to elucidate the hidden structural motifs and their packing in type-II RP. Electron diffraction tomography, performed using individual crystalline nanowires, was used to identify a triclinic unit cell with volume of 5330 Å3, which is the largest unit cell for elemental phosphorus crystals up to now and contains approximately 250 phosphorus atoms. Atomic-resolution STEM imaging, which was performed along different crystal-zone axes, confirmed that the twisted wavy tubular motif is the basic building block of type-II RP. Our study discovered and presented a new variation of building blocks in phosphorus, and it provides insights to clarify the complexities observed in phosphorus as well as other relevant systems. © 2023 Wiley-VCH GmbH. |
| Keyword | Atoms Crystal atomic structure Electron diffraction Electrons High resolution transmission electron microscopy Scanning electron microscopy Tomography Atomic-resolution Diffraction tomography Packing motifs Red phosphorus Resolution scanning Scanning transmission electron microscopy Structure elucidation Twisted pentagonal tube Type II Wavy packing motif |
| URL | 查看原文 |
| Indexed By | EI ; SCI |
| Language | 英语 |
| Funding Project | Basic Science Research Program of the National Research Foundation of Korea["NRF-2022R1A2C4002559","NRF-2021R1C1C2006785","NRF-2017R1A5A1014862","NRF-2022R1A2C2091815"] ; Institute for Basic Science[IBS-R026-D1] ; National Science Foundation of China[22222108] |
| WOS Research Area | Chemistry |
| WOS Subject | Chemistry, Multidisciplinary |
| WOS ID | WOS:001039721200001 |
| Publisher | John Wiley and Sons Inc |
| EI Accession Number | 20233114470890 |
| EI Keywords | Phosphorus |
| EI Classification Number | 741.3 Optical Devices and Systems ; 746 Imaging Techniques ; 804 Chemical Products Generally ; 931.3 Atomic and Molecular Physics ; 933.1.1 Crystal Lattice |
| Original Document Type | Article in Press |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | https://kms.shanghaitech.edu.cn/handle/2MSLDSTB/319441 |
| Collection | 物质科学与技术学院 物质科学与技术学院_PI研究组_马延航组 物质科学与技术学院_博士生 |
| Corresponding Author | Ma, Yanhang; Kim, Kwanpyo |
| Affiliation | 1.Yonsei Univ, Dept Phys, Seoul 03722, South Korea 2.Inst Basic Sci IBS, Ctr Nanomed, Seoul 03722, South Korea 3.Ulsan Natl Inst Sci & Technol UNIST, Dept Phys, Ulsan 44919, South Korea 4.ShanghaiTech Univ, Sch Phys Sci & Technol, Shanghai 201210, Peoples R China 5.ShanghaiTech Univ, Shanghai Key Lab High resolut Electron Microscopy, Shanghai 201210, Peoples R China 6.Sogang Univ, Dept Phys, Seoul 04107, South Korea 7.Korea Res Inst Stand & Sci, Div Ind Metrol, Daejeon 34113, South Korea |
| Corresponding Author Affilication | School of Physical Science and Technology; ShanghaiTech University |
| Recommended Citation GB/T 7714 | Yoon, Jun-Yeong,Lee, Yangjin,Kim, Dong-Gyu,et al. Type-II Red Phosphorus: Wavy Packing of Twisted Pentagonal Tubes[J]. ANGEWANDTE CHEMIE - INTERNATIONAL EDITION,2023,62(36). |
| APA | Yoon, Jun-Yeong.,Lee, Yangjin.,Kim, Dong-Gyu.,Oh, Dong Gun.,Kim, Jin Kyun.,...&Kim, Kwanpyo.(2023).Type-II Red Phosphorus: Wavy Packing of Twisted Pentagonal Tubes.ANGEWANDTE CHEMIE - INTERNATIONAL EDITION,62(36). |
| MLA | Yoon, Jun-Yeong,et al."Type-II Red Phosphorus: Wavy Packing of Twisted Pentagonal Tubes".ANGEWANDTE CHEMIE - INTERNATIONAL EDITION 62.36(2023). |
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