Type-II Red Phosphorus: Wavy Packing of Twisted Pentagonal Tubes

doi:10.1002/anie.202307102

	Type-II Red Phosphorus: Wavy Packing of Twisted Pentagonal Tubes
	Yoon, Jun-Yeong 1,2; Lee, Yangjin 1,2; Kim, Dong-Gyu 1; Oh, Dong Gun 1; Kim, Jin Kyun 3,6,7; Guo, Linshuo4,5 ; Kim, Jungcheol ; Choe, Jeongheon 1; Lee, Kihyun 1,2; Cheong, Hyeonsik 6; Kim, Chae Un 3; Choi, Young Jai 1; Ma, Yanhang4,5 ; Kim, Kwanpyo 1,2
	2023
发表期刊	ANGEWANDTE CHEMIE - INTERNATIONAL EDITION (IF:16.1[JCR-2023],16.2[5-Year])
ISSN	1433-7851
EISSN	1521-3773
卷号	62 期号:36
发表状态	已发表
DOI	10.1002/anie.202307102
摘要	Elemental phosphorus exhibits fascinating structural varieties and versatile properties. The unique nature of phosphorus bonds can lead to the formation of extremely complex structures, and detailed structural information on some phosphorus polymorphs is yet to be investigated. In this study, we investigated an unidentified crystalline phase of phosphorus, type-II red phosphorus (RP), by combining state-of-the-art structural characterization techniques. Electron diffraction tomography, atomic-resolution scanning transmission electron microscopy (STEM), powder X-ray diffraction, and Raman spectroscopy were concurrently used to elucidate the hidden structural motifs and their packing in type-II RP. Electron diffraction tomography, performed using individual crystalline nanowires, was used to identify a triclinic unit cell with volume of 5330 Å3, which is the largest unit cell for elemental phosphorus crystals up to now and contains approximately 250 phosphorus atoms. Atomic-resolution STEM imaging, which was performed along different crystal-zone axes, confirmed that the twisted wavy tubular motif is the basic building block of type-II RP. Our study discovered and presented a new variation of building blocks in phosphorus, and it provides insights to clarify the complexities observed in phosphorus as well as other relevant systems. © 2023 Wiley-VCH GmbH.
关键词	Atoms Crystal atomic structure Electron diffraction Electrons High resolution transmission electron microscopy Scanning electron microscopy Tomography Atomic-resolution Diffraction tomography Packing motifs Red phosphorus Resolution scanning Scanning transmission electron microscopy Structure elucidation Twisted pentagonal tube Type II Wavy packing motif
URL	查看原文
收录类别	EI ; SCI
语种	英语
资助项目	Basic Science Research Program of the National Research Foundation of Korea["NRF-2022R1A2C4002559","NRF-2021R1C1C2006785","NRF-2017R1A5A1014862","NRF-2022R1A2C2091815"] ; Institute for Basic Science[IBS-R026-D1] ; National Science Foundation of China[22222108]
WOS研究方向	Chemistry
WOS类目	Chemistry, Multidisciplinary
WOS记录号	WOS:001039721200001
出版者	John Wiley and Sons Inc
EI入藏号	20233114470890
EI主题词	Phosphorus
EI分类号	741.3 Optical Devices and Systems ; 746 Imaging Techniques ; 804 Chemical Products Generally ; 931.3 Atomic and Molecular Physics ; 933.1.1 Crystal Lattice
原始文献类型	Article in Press
引用统计	正在获取...
文献类型	期刊论文
条目标识符	https://kms.shanghaitech.edu.cn/handle/2MSLDSTB/319441
专题	物质科学与技术学院物质科学与技术学院_PI研究组_马延航组物质科学与技术学院_博士生
通讯作者	Ma, Yanhang; Kim, Kwanpyo
作者单位	1.Yonsei Univ, Dept Phys, Seoul 03722, South Korea 2.Inst Basic Sci IBS, Ctr Nanomed, Seoul 03722, South Korea 3.Ulsan Natl Inst Sci & Technol UNIST, Dept Phys, Ulsan 44919, South Korea 4.ShanghaiTech Univ, Sch Phys Sci & Technol, Shanghai 201210, Peoples R China 5.ShanghaiTech Univ, Shanghai Key Lab High resolut Electron Microscopy, Shanghai 201210, Peoples R China 6.Sogang Univ, Dept Phys, Seoul 04107, South Korea 7.Korea Res Inst Stand & Sci, Div Ind Metrol, Daejeon 34113, South Korea
通讯作者单位	物质科学与技术学院; 上海科技大学
推荐引用方式 GB/T 7714	Yoon, Jun-Yeong,Lee, Yangjin,Kim, Dong-Gyu,et al. Type-II Red Phosphorus: Wavy Packing of Twisted Pentagonal Tubes[J]. ANGEWANDTE CHEMIE - INTERNATIONAL EDITION,2023,62(36).
APA	Yoon, Jun-Yeong.,Lee, Yangjin.,Kim, Dong-Gyu.,Oh, Dong Gun.,Kim, Jin Kyun.,...&Kim, Kwanpyo.(2023).Type-II Red Phosphorus: Wavy Packing of Twisted Pentagonal Tubes.ANGEWANDTE CHEMIE - INTERNATIONAL EDITION,62(36).
MLA	Yoon, Jun-Yeong,et al."Type-II Red Phosphorus: Wavy Packing of Twisted Pentagonal Tubes".ANGEWANDTE CHEMIE - INTERNATIONAL EDITION 62.36(2023).