Correlation of O (1s) and Fe (2p) near edge x-ray absorption fine structure spectra and electrical conductivity of La1-xSrxFe0.75Ni0.25O3-delta

doi:10.1063/1.3246145

	Correlation of O (1s) and Fe (2p) near edge x-ray absorption fine structure spectra and electrical conductivity of La1-xSrxFe0.75Ni0.25O3-delta
	Erat, Selma 1,2; Braun, Artur 1; Ovalle, Alejandro 1; Piamonteze, Cinthia 3; Liu, Zhi4 ; Graule, Thomas 1,5; Gauckler, Ludwig J.2
	2009
发表期刊	APPLIED PHYSICS LETTERS
ISSN	0003-6951
卷号	95 期号:17 页码:-
发表状态	已发表
DOI	10.1063/1.3246145
摘要	A-site substitution of La3+ by Sr2+ in polaron conducting ABO(3)-type perovskite La1-xSrxFe0.75Ni0.25O3-delta causes oxidation of Fe3+ toward Fe4+ and formation of conducting electron holes, as evidenced by Fe (2p) and O (1s) near edge x-ray absorption fine structure spectra. Hole doping is reflected by linear variation of the prepeak ratio e(g)(up arrow)/ ()[t(2g)(down arrow)+e(g)(down arrow)] of oxygen spectra, along with increased conductivity. The significant increase in conductivity due to NiO doping in La1-xSrxFe0.75Ni0.25O3-delta is caused by increased overlap between Fe (3d) and O (2p) and charge transfer from the O (2p) to the Ni (3d) states, as concluded from near edge x-ray absorption fine structure spectra and ligand field multiplet calculations. (C) 2009 American Institute of Physics. ()[doi: 10.1063/1.3246145]
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收录类别	SCI
WOS研究方向	Physics
WOS类目	Physics, Applied
WOS记录号	WOS:000271360400094
出版者	AMER INST PHYSICS
WOS关键词	ELECTRONIC-STRUCTURE ; PHYSICAL-PROPERTIES ; MAGNETIC-PROPERTIES ; TRANSPORT ; NI
引用统计
文献类型	期刊论文
条目标识符	https://kms.shanghaitech.edu.cn/handle/2MSLDSTB/31120
专题	个人在本单位外知识产出
通讯作者	Erat, Selma
作者单位	1.EMPA, Swiss Fed Labs Mat Testing & Res, Lab High Performance Ceram, CH-8600 Dubendorf, Switzerland 2.ETH, Swiss Fed Inst Technol, Dept Mat Nonmetall Inorgan Mat, CH-8093 Zurich, Switzerland 3.Paul Scherrer Inst, Swiss Light Source, CH-5232 Villigen, Switzerland 4.Ernest Orlando Lawrence Berkeley Natl Lab, Adv Light Source, Berkeley, CA 94720 USA 5.Tech Univ Bergakad Freiberg, D-09596 Freiberg, Germany
推荐引用方式 GB/T 7714	Erat, Selma,Braun, Artur,Ovalle, Alejandro,et al. Correlation of O (1s) and Fe (2p) near edge x-ray absorption fine structure spectra and electrical conductivity of La1-xSrxFe0.75Ni0.25O3-delta[J]. APPLIED PHYSICS LETTERS,2009,95(17):-.
APA	Erat, Selma.,Braun, Artur.,Ovalle, Alejandro.,Piamonteze, Cinthia.,Liu, Zhi.,...&Gauckler, Ludwig J..(2009).Correlation of O (1s) and Fe (2p) near edge x-ray absorption fine structure spectra and electrical conductivity of La1-xSrxFe0.75Ni0.25O3-delta.APPLIED PHYSICS LETTERS,95(17),-.
MLA	Erat, Selma,et al."Correlation of O (1s) and Fe (2p) near edge x-ray absorption fine structure spectra and electrical conductivity of La1-xSrxFe0.75Ni0.25O3-delta".APPLIED PHYSICS LETTERS 95.17(2009):-.