消息
×
loading..
Entanglement of charge transfer, hole doping, exchange interaction, and octahedron tilting angle and their influence on the conductivity of La1-xSrxFe0.75Ni0.25O3-delta: A combination of x-ray spectroscopy and diffraction
2010
发表期刊JOURNAL OF APPLIED PHYSICS (IF:2.7[JCR-2023],2.6[5-Year])
ISSN0021-8979
卷号108期号:12页码:-
发表状态已发表
DOI10.1063/1.3517822
摘要

Substitution of La by Sr in the 25% Ni doped charge transfer insulator LaFeO3 leads to structural changes that inflect the electrical conductivity, which is caused by small polaron hopping via charge transfer and exchange interactions. The substitution forms electron holes and causes a structural transition from orthorhombic to rhombohedral symmetry, and then to cubic symmetry. The structural crossover is accompanied by a crossover from the Fe3+-O2--Fe3+ superexchange interaction to the Fe3+-O2--Fe4+ double exchange interaction in the course of substitution, as evidenced by a considerable increase in the conductivity at ambient temperature. The charge transfer and exchange interactions depend on the superexchange angle, which approaches 180 degrees upon increasing Sr concentration. An increase in superexchange angle leads to an increase in overlapping between the O 2p and the Fe/Ni 3d orbitals. (C) 2010 American Institute of Physics. ()[doi:10.1063/1.3517822]

URL查看原文
收录类别SCI
WOS研究方向Physics
WOS类目Physics, Applied
WOS记录号WOS:000285768800136
出版者AMER INST PHYSICS
WOS关键词ABSORPTION-SPECTROSCOPY ; TRANSPORT-PROPERTIES ; PHYSICAL-PROPERTIES ; PHASE-TRANSITION ; CATHODE MATERIAL ; PEROVSKITES ; LA1-XSRXFEO3 ; MANGANITES ; REFINEMENT ; BEHAVIOR
引用统计
正在获取...
文献类型期刊论文
条目标识符https://kms.shanghaitech.edu.cn/handle/2MSLDSTB/31106
专题个人在本单位外知识产出
通讯作者Erat, Selma
作者单位
1.Empa Swiss Fed Labs Mat Sci & Technol, Lab High Performance Ceram, CH-8600 Dubendorf, Switzerland
2.ETH, Dept Mat, Swiss Fed Inst Technol, CH-8093 Zurich, Switzerland
3.Paul Scherrer Inst, Swiss Light Source, CH-5232 Villigen, Switzerland
4.Ernest Orlando Lawrence Berkeley Natl Lab, Adv Light Source, Berkeley, CA 94720 USA
5.Tech Univ Bergakad Freiberg, D-09596 Freiberg, Germany
推荐引用方式
GB/T 7714
Erat, Selma,Braun, Artur,Piamonteze, Cinthia,et al. Entanglement of charge transfer, hole doping, exchange interaction, and octahedron tilting angle and their influence on the conductivity of La1-xSrxFe0.75Ni0.25O3-delta: A combination of x-ray spectroscopy and diffraction[J]. JOURNAL OF APPLIED PHYSICS,2010,108(12):-.
APA Erat, Selma.,Braun, Artur.,Piamonteze, Cinthia.,Liu, Zhi.,Ovalle, Alejandro.,...&Gauckler, Ludwig J..(2010).Entanglement of charge transfer, hole doping, exchange interaction, and octahedron tilting angle and their influence on the conductivity of La1-xSrxFe0.75Ni0.25O3-delta: A combination of x-ray spectroscopy and diffraction.JOURNAL OF APPLIED PHYSICS,108(12),-.
MLA Erat, Selma,et al."Entanglement of charge transfer, hole doping, exchange interaction, and octahedron tilting angle and their influence on the conductivity of La1-xSrxFe0.75Ni0.25O3-delta: A combination of x-ray spectroscopy and diffraction".JOURNAL OF APPLIED PHYSICS 108.12(2010):-.
条目包含的文件 下载所有文件
文件名称/大小 文献类型 版本类型 开放类型 使用许可
个性服务
查看访问统计
谷歌学术
谷歌学术中相似的文章
[Erat, Selma]的文章
[Braun, Artur]的文章
[Piamonteze, Cinthia]的文章
百度学术
百度学术中相似的文章
[Erat, Selma]的文章
[Braun, Artur]的文章
[Piamonteze, Cinthia]的文章
必应学术
必应学术中相似的文章
[Erat, Selma]的文章
[Braun, Artur]的文章
[Piamonteze, Cinthia]的文章
相关权益政策
暂无数据
收藏/分享
文件名: 10.1063@1.3517822.pdf
格式: Adobe PDF
所有评论 (0)
暂无评论
 

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。