A generalizable method for the construction of MOF@polymer functional composites through surface-initiated atom transfer radical polymerization
2019-02-14
发表期刊CHEMICAL SCIENCE (IF:7.6[JCR-2023],8.0[5-Year])
ISSN2041-6520
卷号10期号:6页码:1816-1822
发表状态已发表
DOI10.1039/c8sc03520b
摘要We report a generalizable approach to construct MOF@polymer functional composites through surface-initiated atom transfer radical polymerization (SI-ATRP). Unlike conventional SI-ATRP that requires covalent pre-anchoring of the initiating group on substrate surfaces, in our approach, a rationally designed random copolymer (RCP) macroinitiator first self-assembles on MOF surfaces through interchain hydrogen bond crosslinking. Subsequent polymerization in the presence of a crosslinking monomer covalently threads these polymer chains into a robust network, physically confining the MOF particle inside the polymer shell. We demonstrated the universality of this approach by growing various polymers on five MOFs of different metals (Zr, Zn, Co, Al, and Cr) with complete control over shell thickness, functionality and layer sequence while still retaining the inherent porosity of the MOFs. Moreover, the wettability of UiO-66 can be continuously tuned from superhydrophilic to superhydrophobic simply through judicious monomer(s) selection. We also demonstrated that a 7 nm polystyrene shell can effectively shield UiO-66 particles against 1 M H2SO4 and 1 M NaOH at elevated temperature, enabling their potential application in demanding chemical environments.
收录类别SCI ; SCIE ; EI
语种英语
资助项目National Natural Science Foundation of China[21701110]
WOS研究方向Chemistry
WOS类目Chemistry, Multidisciplinary
WOS记录号WOS:000458024700028
出版者ROYAL SOC CHEMISTRY
EI入藏号20190606486616
EI主题词Crosslinking ; Free radical reactions ; Hydrogen bonds ; Monomers ; Polymerization ; Sodium hydroxide
EI分类号Physical Chemistry:801.4 ; Chemical Reactions:802.2 ; Chemical Products Generally:804 ; Polymerization:815.2
WOS关键词METAL-ORGANIC FRAMEWORKS ; MIXED-MATRIX MEMBRANES ; PHOTOTHERMAL THERAPY ; NANOPARTICLES ; CHEMISTRY ; DELIVERY ; FACILE
原始文献类型Article
引用统计
正在获取...
文献类型期刊论文
条目标识符https://kms.shanghaitech.edu.cn/handle/2MSLDSTB/30302
专题物质科学与技术学院_博士生
物质科学与技术学院_PI研究组_李涛组
物质科学与技术学院_PI研究组_yongjin lee组
物质科学与技术学院_PI研究组_于奕组
物质科学与技术学院_硕士生
物质科学与技术学院_本科生
通讯作者Li, Tao
作者单位
ShanghaiTech Univ, Sch Phys Sci & Technol, Shanghai 201210, Peoples R China
第一作者单位物质科学与技术学院
通讯作者单位物质科学与技术学院
第一作者的第一单位物质科学与技术学院
推荐引用方式
GB/T 7714
He, Sanfeng,Wang, Hongliang,Zhang, Cuizheng,et al. A generalizable method for the construction of MOF@polymer functional composites through surface-initiated atom transfer radical polymerization[J]. CHEMICAL SCIENCE,2019,10(6):1816-1822.
APA He, Sanfeng.,Wang, Hongliang.,Zhang, Cuizheng.,Zhang, Songwei.,Yu, Yi.,...&Li, Tao.(2019).A generalizable method for the construction of MOF@polymer functional composites through surface-initiated atom transfer radical polymerization.CHEMICAL SCIENCE,10(6),1816-1822.
MLA He, Sanfeng,et al."A generalizable method for the construction of MOF@polymer functional composites through surface-initiated atom transfer radical polymerization".CHEMICAL SCIENCE 10.6(2019):1816-1822.
条目包含的文件
文件名称/大小 文献类型 版本类型 开放类型 使用许可
个性服务
查看访问统计
谷歌学术
谷歌学术中相似的文章
[He, Sanfeng]的文章
[Wang, Hongliang]的文章
[Zhang, Cuizheng]的文章
百度学术
百度学术中相似的文章
[He, Sanfeng]的文章
[Wang, Hongliang]的文章
[Zhang, Cuizheng]的文章
必应学术
必应学术中相似的文章
[He, Sanfeng]的文章
[Wang, Hongliang]的文章
[Zhang, Cuizheng]的文章
相关权益政策
暂无数据
收藏/分享
所有评论 (0)
暂无评论
 

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。