Asymmetric synthesis of highly sterically congested α-tertiary amines via organocatalyzed kinetic resolution

doi:10.1039/d3cc00653k

	Asymmetric synthesis of highly sterically congested α-tertiary amines via organocatalyzed kinetic resolution
	Jiang, Qianwen; Xie, Wansen; Yang, Xiaoyu
	2023
发表期刊	CHEMICAL COMMUNICATIONS (IF:4.3[JCR-2023],4.4[5-Year])
ISSN	1359-7345
EISSN	1364-548X
卷号	59 期号:32 页码:4762-4765
发表状态	已发表
DOI	10.1039/d3cc00653k
摘要	The asymmetric synthesis of highly sterically congested α-tertiary amines was achieved by an organocatalyzed kinetic resolution (KR) protocol, which were otherwise difficult to access. A variety of substituted N-aryl α-tertiary amines bearing 2-substitued phenyl groups were kinetically resolved through the asymmetric C-H amination reaction, affording good to high KR performances. © 2023 The Royal Society of Chemistry.
关键词	Amines Amination reaction Asymmetric synthesis C-H amination Kinetic resolution Performance Phenyl group Sterically congested Tertiary amine
URL	查看原文
收录类别	SCI ; EI
语种	英语
资助项目	NSFC[
WOS研究方向	Chemistry
WOS类目	Chemistry, Multidisciplinary
WOS记录号	WOS:000968496000001
出版者	Royal Society of Chemistry
EI入藏号	20231513872436
EI主题词	Kinetics
EI分类号	631.1 Fluid Flow, General ; 804.1 Organic Compounds ; 931 Classical Physics ; Quantum Theory ; Relativity
原始文献类型	Article in Press
引用统计	正在获取...
文献类型	期刊论文
条目标识符	https://kms.shanghaitech.edu.cn/handle/2MSLDSTB/297908
专题	物质科学与技术学院物质科学与技术学院_PI研究组_杨晓瑜组物质科学与技术学院_硕士生物质科学与技术学院_博士生
通讯作者	Yang, Xiaoyu
作者单位	ShanghaiTech Univ, Sch Phys Sci & Technol, Shanghai 201210, Peoples R China
第一作者单位	物质科学与技术学院
通讯作者单位	物质科学与技术学院
第一作者的第一单位	物质科学与技术学院
推荐引用方式 GB/T 7714	Jiang, Qianwen,Xie, Wansen,Yang, Xiaoyu. Asymmetric synthesis of highly sterically congested α-tertiary amines via organocatalyzed kinetic resolution[J]. CHEMICAL COMMUNICATIONS,2023,59(32):4762-4765.
APA	Jiang, Qianwen,Xie, Wansen,&Yang, Xiaoyu.(2023).Asymmetric synthesis of highly sterically congested α-tertiary amines via organocatalyzed kinetic resolution.CHEMICAL COMMUNICATIONS,59(32),4762-4765.
MLA	Jiang, Qianwen,et al."Asymmetric synthesis of highly sterically congested α-tertiary amines via organocatalyzed kinetic resolution".CHEMICAL COMMUNICATIONS 59.32(2023):4762-4765.