Cerium-Catalyzed Formal Cycloaddition of Cycloalkanols with Alkenes through Dual Photoexcitation

doi:10.1021/jacs.8b08781

	Cerium-Catalyzed Formal Cycloaddition of Cycloalkanols with Alkenes through Dual Photoexcitation
	Hu, Anhua; Chen, Yilin; Guo, Jing-Jing; Yu, Na; An, Qing; Zuo, Zhiwei
	2018-10-24
发表期刊	JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (IF:14.4[JCR-2023],14.8[5-Year])
ISSN	0002-7863
卷号	140 期号:42 页码:13580-13585
发表状态	已发表
DOI	10.1021/jacs.8b08781
摘要	We describe a synergistic utilization of cerium photocatalysis and photoinduced electron transfer catalysis that enables an atom- and step-economical ring expansion of readily available cycloalkanols. This operationally simple protocol provides rapid access to privileged and synthetically challenging bridged lactones. The mild catalytic manifold has been adapted to continuous flow for scale-up applications and employed for the concise synthesis of polycyclic core of nepalactones.
收录类别	SCI ; SCIE ; IC ; CCR ; EI
语种	英语
资助项目	Shanghai Sailing Program[18YF1416900]
WOS研究方向	Chemistry
WOS类目	Chemistry, Multidisciplinary
WOS记录号	WOS:000448755200013
出版者	AMER CHEMICAL SOC
EI入藏号	20184205954912
EI主题词	Cerium
EI分类号	Rare Earth Metals:547.2 ; Chemical Reactions:802.2
WOS关键词	C-C BOND ; VISIBLE-LIGHT PHOTOCATALYSIS ; SATURATED ALIPHATIC-ALCOHOLS ; ELECTRON-TRANSFER PROCESSES ; METAL CHARGE-TRANSFER ; PHOTOREDOX CATALYSIS ; ELECTROGENERATED CHEMILUMINESCENCE ; REDUCTION POTENTIALS ; CLEAVAGE REACTIONS ; LEAD-TETRAACETATE
原始文献类型	Article
引用统计	正在获取...
文献类型	期刊论文
条目标识符	https://kms.shanghaitech.edu.cn/handle/2MSLDSTB/28289
专题	物质科学与技术学院_PI研究组_左智伟组物质科学与技术学院_公共科研平台_分析测试平台物质科学与技术学院_硕士生物质科学与技术学院_博士生
通讯作者	Zuo, Zhiwei
作者单位	ShanghaiTech Univ, Sch Phys Sci & Technol, Shanghai 201210, Peoples R China
第一作者单位	物质科学与技术学院
通讯作者单位	物质科学与技术学院
第一作者的第一单位	物质科学与技术学院
推荐引用方式 GB/T 7714	Hu, Anhua,Chen, Yilin,Guo, Jing-Jing,et al. Cerium-Catalyzed Formal Cycloaddition of Cycloalkanols with Alkenes through Dual Photoexcitation[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2018,140(42):13580-13585.
APA	Hu, Anhua,Chen, Yilin,Guo, Jing-Jing,Yu, Na,An, Qing,&Zuo, Zhiwei.(2018).Cerium-Catalyzed Formal Cycloaddition of Cycloalkanols with Alkenes through Dual Photoexcitation.JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,140(42),13580-13585.
MLA	Hu, Anhua,et al."Cerium-Catalyzed Formal Cycloaddition of Cycloalkanols with Alkenes through Dual Photoexcitation".JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 140.42(2018):13580-13585.