Catalytic Electrophilic Alkylation of p-Quinones through a Redox Chain Reaction

doi:10.1002/anie.201702885

	Catalytic Electrophilic Alkylation of p-Quinones through a Redox Chain Reaction
	Xu, Xiao-Long; Li, Zhi
	2017-07-03
发表期刊	ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (IF:16.1[JCR-2023],16.2[5-Year])
ISSN	1433-7851
卷号	56 期号:28 页码:8196-8200
发表状态	已发表
DOI	10.1002/anie.201702885
摘要	Allylation and benzylation of p-quinones was achieved through an unusual redox chain reaction. Mechanistic studies suggest that the existence of trace hydroquinone initiates a redox chain reaction that consists of a Lewis acid catalyzed Friedel-Crafts alkylation and a subsequent redox equilibrium that regenerates hydroquinone. The electrophiles could be various allylic and benzylic esters. The addition of Hantzsch ester as an initiator improves the efficiency of the reaction.
关键词	Alkylation Quinones Redox Chemistry Synthetic Methods
收录类别	SCI ; IC ; CCR ; EI
语种	英语
资助项目	National Natural Science Foundation of China[21673141]
WOS研究方向	Chemistry
WOS类目	Chemistry, Multidisciplinary
WOS记录号	WOS:000404140900028
出版者	WILEY-V C H VERLAG GMBH
EI入藏号	20172403763510
EI主题词	Chains ; Esters ; Phenols
WOS关键词	C-H FUNCTIONALIZATION ; COENZYME Q(10) ; AEROBIC OXIDATION ; TANDEM CATALYSIS ; PHOTOSYSTEM-I ; N-ALKYLATION ; METAL-FREE ; ALCOHOLS ; MECHANISM ; HYDROQUINONES
原始文献类型	Article
通讯作者	Li, Zhi
引用统计	正在获取...
文献类型	期刊论文
条目标识符	https://kms.shanghaitech.edu.cn/handle/2MSLDSTB/2587
专题	物质科学与技术学院物质科学与技术学院_PI研究组_李智组物质科学与技术学院_博士生
通讯作者	Li, Zhi
作者单位	ShanghaiTech Univ, Sch Phys Sci & Technol, 393 Middle Huaxia Rd, Shanghai 201210, Peoples R China
第一作者单位	物质科学与技术学院
通讯作者单位	物质科学与技术学院
第一作者的第一单位	物质科学与技术学院
推荐引用方式 GB/T 7714	Xu, Xiao-Long,Li, Zhi. Catalytic Electrophilic Alkylation of p-Quinones through a Redox Chain Reaction[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2017,56(28):8196-8200.
APA	Xu, Xiao-Long,&Li, Zhi.(2017).Catalytic Electrophilic Alkylation of p-Quinones through a Redox Chain Reaction.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,56(28),8196-8200.
MLA	Xu, Xiao-Long,et al."Catalytic Electrophilic Alkylation of p-Quinones through a Redox Chain Reaction".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 56.28(2017):8196-8200.