Stereoselective synthesis of beta-rhamnopyranosides via gold(I)-catalyzed glycosylation with 2-alkynyl-4-nitro-benzoate donors

doi:10.1039/c5ob02551f

	Stereoselective synthesis of beta-rhamnopyranosides via gold(I)-catalyzed glycosylation with 2-alkynyl-4-nitro-benzoate donors
	Zhu, Yugen 1; Shen, Zhengnan2 ; Li, Wei 1; Yu, Biao1
	2016
发表期刊	ORGANIC & BIOMOLECULAR CHEMISTRY (IF:2.9[JCR-2023],2.8[5-Year])
ISSN	1477-0520
卷号	14 期号:5 页码:1536-1539
发表状态	已发表
DOI	10.1039/c5ob02551f
摘要	Stereoselective beta-rhamnopyranosylation remains a challenge, due to the unfavorable anomeric effect and steric hindrance of the C2-substituent; herein, this challenge is addressed with a gold(I)-catalyzed S(N)2-like glycosylation protocol employing alpha-rhamnopyranosyl 2-alkynyl-4-nitro-benzoates as donors.
收录类别	SCI ; IC ; CCR ; EI
语种	英语
资助项目	Natural Science Foundation of China[21432012] ; Natural Science Foundation of China[21372253]
WOS研究方向	Chemistry
WOS类目	Chemistry, Organic
WOS记录号	WOS:000369600000003
出版者	ROYAL SOC CHEMISTRY
EI入藏号	20160601892341
EI主题词	Catalysis ; Glycosylation ; Gold ; Stereochemistry
EI分类号	Precious Metals:547.1 ; Chemistry:801 ; Biochemistry:801.2 ; Chemical Reactions:802.2
WOS关键词	L-RHAMNOSIDIC LINKAGES ; REDUCTIVE RADICAL FRAGMENTATION ; ORTHO-ALKYNYLBENZOATES ; PROTECTING GROUP ; STEREOCONTROLLED SYNTHESIS ; STEREOSPECIFIC SYNTHESIS ; EFFICIENT GENERATION ; D-MANNOPYRANOSIDES ; REPEATING UNIT ; OLIGOSACCHARIDES
原始文献类型	Article
引用统计	正在获取...
文献类型	期刊论文
条目标识符	https://kms.shanghaitech.edu.cn/handle/2MSLDSTB/2574
专题	物质科学与技术学院物质科学与技术学院_特聘教授组_俞飚组物质科学与技术学院_博士生
通讯作者	Yu, Biao
作者单位	1.Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Bioorgan & Nat Prod Chem, 345 Lingling Rd, Shanghai 200032, Peoples R China 2.ShanghaiTech Univ, Sch Phys Sci & Technol, 100 Haike Rd, Shanghai 201210, Peoples R China
推荐引用方式 GB/T 7714	Zhu, Yugen,Shen, Zhengnan,Li, Wei,et al. Stereoselective synthesis of beta-rhamnopyranosides via gold(I)-catalyzed glycosylation with 2-alkynyl-4-nitro-benzoate donors[J]. ORGANIC & BIOMOLECULAR CHEMISTRY,2016,14(5):1536-1539.
APA	Zhu, Yugen,Shen, Zhengnan,Li, Wei,&Yu, Biao.(2016).Stereoselective synthesis of beta-rhamnopyranosides via gold(I)-catalyzed glycosylation with 2-alkynyl-4-nitro-benzoate donors.ORGANIC & BIOMOLECULAR CHEMISTRY,14(5),1536-1539.
MLA	Zhu, Yugen,et al."Stereoselective synthesis of beta-rhamnopyranosides via gold(I)-catalyzed glycosylation with 2-alkynyl-4-nitro-benzoate donors".ORGANIC & BIOMOLECULAR CHEMISTRY 14.5(2016):1536-1539.