Electrically regulating nonlinear optical limiting of metal-organic framework film

doi:10.1038/s41467-022-34139-2

	Electrically regulating nonlinear optical limiting of metal-organic framework film
	Ma, Zhi Zhou 1; Li, Qiao Hong 1; Wang, Zirui1,2 ; Gu, Zhi Gang 1,3; Zhang, Jian 1,3
	2022-10-26
发表期刊	NATURE COMMUNICATIONS (IF:14.7[JCR-2023],16.1[5-Year])
ISSN	2041-1723
卷号	13 期号:1
发表状态	已发表
DOI	10.1038/s41467-022-34139-2
摘要	Regulating nonlinear optical (NLO) property of metal−organic frameworks (MOFs) is of pronounced significance for their scientific research and practical application, but the regulation through external stimuli is still a challenging task. Here we prepare and electrically control the nonlinear optical regulation of conductive MOFs Cu-HHTP films with [001]- (Cu-HHTP) and [100]-orientations (Cu-HHTP). Z-scan results show that the nonlinear absorption coefficient (β) of Cu-HHTP film (7.60 × 10 m/W) is much higher than that of Cu-HHTP film (0.84 × 10 m/W) at 0 V and the β of Cu-HHTP and Cu-HHTP films gradually increase to 3.84 × 10 and 1.71 × 10 m/W at 10 V by increasing the applied voltage, respectively. Due to 2D Cu-HHTP having anisotropy of charge transfer in different orientations, the NLO of MOFs film can be dependent on their growth orientations and improved by tuning the electrical field. This study provides more avenues for the regulation and NLO applications of MOFs.
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收录类别	SCI
语种	英语
Scopus 记录号	2-s2.0-85140644198
来源库	Scopus
引用统计	正在获取...
文献类型	期刊论文
条目标识符	https://kms.shanghaitech.edu.cn/handle/2MSLDSTB/243353
专题	物质科学与技术学院_博士生
作者单位	1.State Key Laboratory of Structural Chemistry,Fujian Institute of Research on the Structure of Matter,Chinese Academy of Sciences,Fuzhou,Fujian,350002,China 2.School of Physical Science and Technology,ShanghaiTech University,Shanghai,201210,China 3.Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China,Fuzhou,Fujian,350108,China
推荐引用方式 GB/T 7714	Ma, Zhi Zhou,Li, Qiao Hong,Wang, Zirui,et al. Electrically regulating nonlinear optical limiting of metal-organic framework film[J]. NATURE COMMUNICATIONS,2022,13(1).
APA	Ma, Zhi Zhou,Li, Qiao Hong,Wang, Zirui,Gu, Zhi Gang,&Zhang, Jian.(2022).Electrically regulating nonlinear optical limiting of metal-organic framework film.NATURE COMMUNICATIONS,13(1).
MLA	Ma, Zhi Zhou,et al."Electrically regulating nonlinear optical limiting of metal-organic framework film".NATURE COMMUNICATIONS 13.1(2022).