上海科技大学知识管理系统

Hydrogen-bonded molecules and their dynamics are significantly important in chemistry and biology due to their widespread functionality. Besides their natural abundance and diversity, applications of molecules with dynamic conformations in artificial networks allow information storage and molecular motor design on the nanometer scale. Here, we report hydrogen-bonded molecular networks with tunable helical conformation on metal surfaces. The dynamics of helical conformation in two-dimensional hydrogen-bond networks are triggered and resolved by scanning probe microscopy at the single-molecule level. In combination with theoretical calculations, the surface-specific hydrogen bonds are identified as the origin of the dynamic helical conformation. Our results provide a distinctive access to molecular architecture with tunable helical conformation driven by hydrogen-bond interaction on surfaces.