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Quantitative Evaluation of Loss Capability for In Situ Conductive Phase Enhanced Microwave Absorption of High-Entropy Transition Metal Oxides
2022-08-25
发表期刊ADVANCED FUNCTIONAL MATERIALS (IF:18.5[JCR-2023],19.6[5-Year])
ISSN1616-301X
EISSN1616-3028
卷号32
发表状态已发表
DOI10.1002/adfm.202205325
摘要

High-entropy oxides (HEO) with high stability and designability are potential microwave absorbers that serve in harsh environments. However, loss design is critical for the absorption performance of HEO due to its weak intrinsic loss capability. Inadequate loss ability results in considerable secondary reflection. Here, an in situ conductive heterogeneous phase is constructed in (Fe0.2xCo0.2Ni0.2Cr0.2Mn0.2)(3)O-4 (x = 1-5) using a reductive circumstance, to form a dual-phase composite. Both the ohmic and dielectric loss are enhanced as the conductive phase is introduced, while great impedance matching condition is well maintained. Hence, the composites can achieve substantial absorption across the whole X or Ku band with a thin thickness. Furthermore, key efforts are made to reveal the relationship between the absorbing performance and loss capability of an absorber. The analytical expression of the theoretical threshold of attenuation constant is derived. Based on the statistics of experimental data, the broad feasibility and practicability of the proposed theoretical threshold of attenuation constant are confirmed and discussed. Combined with both the theoretical and experimental studies, the mechanism by which the conductive phase contributes to increased absorption is also disclosed, providing an effective basis for the loss design of broadband microwave absorbers.

关键词microwave absorbers theoretical design loss capability high-entropy oxides in-situ heterogeneous phases
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收录类别SCI ; SCIE ; EI
语种英语
资助项目Science and Technology Commission of Shanghai Municipality, Shanghai Sailing Program[21YF1454600]
WOS研究方向Chemistry ; Science & Technology - Other Topics ; Materials Science ; Physics
WOS类目Chemistry, Multidisciplinary ; Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Physics, Applied ; Physics, Condensed Matter
WOS记录号WOS:000824853800001
出版者WILEY-V C H VERLAG GMBH
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文献类型期刊论文
条目标识符https://kms.shanghaitech.edu.cn/handle/2MSLDSTB/214745
专题物质科学与技术学院_硕士生
物质科学与技术学院_特聘教授组_宋力昕组
物质科学与技术学院_博士生
共同第一作者Deng, Ruixiang
通讯作者Deng, Ruixiang; Zhang, Tao
作者单位
1.Chinese Acad Sci, Shanghai Inst Ceram, Key Lab Inorgan Coating Mat CAS, Shanghai 200050, Peoples R China
2.ShanghaiTech Univ, Sch Phys Sci & Technol, Shanghai 201210, Peoples R China
3.Univ Chinese Acad Sci, Hangzhou Inst Adv Study, Sch Chem & Mat Sci, Hangzhou 310024, Peoples R China
第一作者单位物质科学与技术学院
推荐引用方式
GB/T 7714
Dai, Guohao,Deng, Ruixiang,Zhang, Tao,et al. Quantitative Evaluation of Loss Capability for In Situ Conductive Phase Enhanced Microwave Absorption of High-Entropy Transition Metal Oxides[J]. ADVANCED FUNCTIONAL MATERIALS,2022,32.
APA Dai, Guohao,Deng, Ruixiang,Zhang, Tao,Yu, Yun,&Song, Lixin.(2022).Quantitative Evaluation of Loss Capability for In Situ Conductive Phase Enhanced Microwave Absorption of High-Entropy Transition Metal Oxides.ADVANCED FUNCTIONAL MATERIALS,32.
MLA Dai, Guohao,et al."Quantitative Evaluation of Loss Capability for In Situ Conductive Phase Enhanced Microwave Absorption of High-Entropy Transition Metal Oxides".ADVANCED FUNCTIONAL MATERIALS 32(2022).
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