Principles and Applications of Enantioselective Hydroformylation of Terminal Disubstituted Alkenes

doi:10.1021/acscatal.5b01300

	Principles and Applications of Enantioselective Hydroformylation of Terminal Disubstituted Alkenes
	Deng, Yuchao1,2 ; Wang, Hui1,2 ; Sun, Yuhan 1; Wang, Xiao 1,3,4
	2015-11
发表期刊	ACS CATALYSIS (IF:11.3[JCR-2023],12.6[5-Year])
ISSN	2155-5435
卷号	5 期号:11 页码:6828-6837
发表状态	已发表
DOI	10.1021/acscatal.5b01300
摘要	Asymmetric hydroformylation has been primarily focused on monosubstituted and 1,2-disubstituted alkenes. In this Perspective, progress in enantioselective hydroformylation of terminal disubstituted alkenes is outlined on the basis of different categories of substrates. The origins of the commonly observed low degree of enantioselectivity are discussed. Examples with unconventional regioselectivity are also rationalized.
关键词	hydroformylation homogeneous catalysis oxo products terminal disubstituted alkene enantioselectivity chiral pocket linear aldehyde regioselectivity
收录类别	SCI ; EI
语种	英语
WOS研究方向	Chemistry
WOS类目	Chemistry, Physical
WOS记录号	WOS:000364441300073
出版者	AMER CHEMICAL SOC
EI入藏号	20154601551080
EI主题词	Catalysis ; Hydrocarbons ; Hydroformylation ; Regioselectivity
EI分类号	Physical Chemistry:801.4 ; Chemical Reactions:802.2 ; Chemical Operations:802.3 ; Organic Compounds:804.1
WOS关键词	CATALYZED ASYMMETRIC HYDROFORMYLATION ; PHOSPHINE-PHOSPHITE LIGANDS ; RHODIUM(I) COMPLEXES ; DIPHOSPHITE LIGANDS ; DIASTEREOSELECTIVE HYDROFORMYLATION ; 1,1-DISUBSTITUTED ALKENES ; DIAZAPHOSPHOLANE LIGANDS ; UNSATURATED ESTERS ; ALLYLIC ALCOHOLS ; ARYL ALKENES
原始文献类型	Article
引用统计	正在获取...
文献类型	期刊论文
条目标识符	https://kms.shanghaitech.edu.cn/handle/2MSLDSTB/2095
专题	物质科学与技术学院物质科学与技术学院_博士生 2060研究院
通讯作者	Wang, Xiao
作者单位	1.Chinese Acad Sci, Shanghai Adv Res Inst, CAS Key Lab Low Carbon Convers Sci & Engn, Shanghai 201210, Peoples R China 2.Shanghai Tech Univ, Sch Phys Sci & Technol, Shanghai 201210, Peoples R China 3.Harvard Univ, Sch Med, Harvard NeuroDiscovery Ctr, Cambridge, MA 02139 USA 4.Brigham & Womens Hosp, Cambridge, MA 02139 USA
第一作者单位	物质科学与技术学院
推荐引用方式 GB/T 7714	Deng, Yuchao,Wang, Hui,Sun, Yuhan,et al. Principles and Applications of Enantioselective Hydroformylation of Terminal Disubstituted Alkenes[J]. ACS CATALYSIS,2015,5(11):6828-6837.
APA	Deng, Yuchao,Wang, Hui,Sun, Yuhan,&Wang, Xiao.(2015).Principles and Applications of Enantioselective Hydroformylation of Terminal Disubstituted Alkenes.ACS CATALYSIS,5(11),6828-6837.
MLA	Deng, Yuchao,et al."Principles and Applications of Enantioselective Hydroformylation of Terminal Disubstituted Alkenes".ACS CATALYSIS 5.11(2015):6828-6837.