A novel thin solid electrolyte film and its application in all-solid-state battery at room temperature
2018-05
发表期刊IONICS (IF:2.4[JCR-2023],2.6[5-Year])
ISSN0947-7047
卷号24期号:5页码:1545-1551
发表状态已发表
DOI10.1007/s11581-017-2353-x
摘要A thin Li7La3Zr2O12 (LLZO) film of several micrometers was prepared by a novel method, which underwent the changes from micro-sized particles, nanoparticle slurry, and the final thin film. The LLZO film exhibited a high stability with metallic Li. The all-solid-state battery was composed by Li metal anode, a mixture cathode (LiCoO2 and LLZO), and the solid electrolyte of a composite of LLZO and LITFSI film. At room temperature, the Li/composite of LLZO and LITFSI/LCO cell showed a discharge capacity of 119.3 mAh g(-1) at a current density of 0.21 mA cm(-2) after 45 cycles, which was approximately 100% of that of the second cycle. Electrochemical impedance spectroscopy showed the reduction of the radius in low-frequency semicircle, demonstrating an improvement of interfacial contact between LLZO and LCO during the cycling.
关键词All-solid-state batteries Lithium batteries Solid electrolytes Garnets Membranes
收录类别SCI ; SCIE ; EI
语种英语
资助项目National Natural Science Foundation of China[51371186]
WOS研究方向Chemistry ; Electrochemistry ; Physics
WOS类目Chemistry, Physical ; Electrochemistry ; Physics, Condensed Matter
WOS记录号WOS:000430513400031
出版者SPRINGER HEIDELBERG
WOS关键词LITHIUM-ION CONDUCTION ; POLYMER ELECTROLYTES ; GARNET ; LI7LA3ZR2O12 ; LICOO2 ; CHALLENGES
原始文献类型Article
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文献类型期刊论文
条目标识符https://kms.shanghaitech.edu.cn/handle/2MSLDSTB/20841
专题物质科学与技术学院
物质科学与技术学院_特聘教授组_韩伟强组
物质科学与技术学院_特聘教授组_温兆银组
物质科学与技术学院_博士生
通讯作者Han, Wei-Qiang
作者单位
1.Chinese Acad Sci, Ningbo Inst Ind Technol, Ningbo 315200, Zhejiang, Peoples R China
2.ShanghaiTech Univ, Sch Phys Sci & Technol, Shanghai 201210, Peoples R China
3.Chinese Acad Sci, Shanghai Inst Ceram, Shanghai 200050, Peoples R China
4.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
5.Zhejiang Univ, Dept Mat Sci & Engn, Hangzhou 310027, Zhejiang, Peoples R China
第一作者单位物质科学与技术学院
通讯作者单位物质科学与技术学院
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GB/T 7714
Yan, Xufeng,Li, Zhuobin,Ying, Hangjun,et al. A novel thin solid electrolyte film and its application in all-solid-state battery at room temperature[J]. IONICS,2018,24(5):1545-1551.
APA Yan, Xufeng.,Li, Zhuobin.,Ying, Hangjun.,Nie, Feng.,Xue, Lixin.,...&Han, Wei-Qiang.(2018).A novel thin solid electrolyte film and its application in all-solid-state battery at room temperature.IONICS,24(5),1545-1551.
MLA Yan, Xufeng,et al."A novel thin solid electrolyte film and its application in all-solid-state battery at room temperature".IONICS 24.5(2018):1545-1551.
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