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Room-temperature ductile inorganic semiconductor | |
2018-05 | |
发表期刊 | NATURE MATERIALS (IF:37.2[JCR-2023],44.0[5-Year]) |
ISSN | 1476-1122 |
卷号 | 17期号:5页码:421-+ |
发表状态 | 已发表 |
DOI | 10.1038/s41563-018-0047-z |
摘要 | Ductility is common in metals and metal-based alloys, but is rarely observed in inorganic semiconductors and ceramic insulators. In particular, room-temperature ductile inorganic semiconductors were not known until now. Here, we report an inorganic alpha-Ag2S semiconductor that exhibits extraordinary metal-like ductility with high plastic deformation strains at room temperature. Analysis of the chemical bonding reveals systems of planes with relatively weak atomic interactions in the crystal structure. In combination with irregularly distributed silver-silver and sulfur-silver bonds due to the silver diffusion, they suppress the cleavage of the material, and thus result in unprecedented ductility. This work opens up the possibility of searching for ductile inorganic semiconductors/ceramics for flexible electronic devices. |
收录类别 | SCI ; SCIE ; EI |
语种 | 英语 |
资助项目 | Shanghai Government[15JC1400301] ; Shanghai Government[16XD1403900] |
WOS研究方向 | Chemistry ; Materials Science ; Physics |
WOS类目 | Chemistry, Physical ; Materials Science, Multidisciplinary ; Physics, Applied ; Physics, Condensed Matter |
WOS记录号 | WOS:000430942800018 |
出版者 | NATURE PUBLISHING GROUP |
EI入藏号 | 20181505002018 |
EI主题词 | Chemical analysis ; Chemical bonds ; Crystal atomic structure ; Ductility ; Silver compounds |
WOS关键词 | ELECTRON LOCALIZABILITY ; HIGH-STRENGTH ; DEFORMATION ; BEHAVIOR ; METALS ; DISLOCATION ; CRYSTALS ; TITANIUM ; TI3SIC2 ; COPPER |
原始文献类型 | Article |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | https://kms.shanghaitech.edu.cn/handle/2MSLDSTB/20206 |
专题 | 物质科学与技术学院 物质科学与技术学院_特聘教授组_陈立东组 物质科学与技术学院_博士生 |
通讯作者 | Shi, Xun; Grin, Yuri; Chen, Lidong |
作者单位 | 1.Chinese Acad Sci, Shanghai Inst Ceram, State Key Lab High Performance Ceram & Superfine, Shanghai, Peoples R China 2.Shanghai Tech Univ, Shanghai, Peoples R China 3.Univ Chinese Acad Sci, Beijing, Peoples R China 4.Max Planck Inst Chem Phys Fester Stoffe, Dresden, Germany |
推荐引用方式 GB/T 7714 | Shi, Xun,Chen, Hongyi,Hao, Feng,et al. Room-temperature ductile inorganic semiconductor[J]. NATURE MATERIALS,2018,17(5):421-+. |
APA | Shi, Xun.,Chen, Hongyi.,Hao, Feng.,Liu, Ruiheng.,Wang, Tuo.,...&Chen, Lidong.(2018).Room-temperature ductile inorganic semiconductor.NATURE MATERIALS,17(5),421-+. |
MLA | Shi, Xun,et al."Room-temperature ductile inorganic semiconductor".NATURE MATERIALS 17.5(2018):421-+. |
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