Room-temperature ductile inorganic semiconductor
2018-05
发表期刊NATURE MATERIALS (IF:37.2[JCR-2023],44.0[5-Year])
ISSN1476-1122
卷号17期号:5页码:421-+
发表状态已发表
DOI10.1038/s41563-018-0047-z
摘要Ductility is common in metals and metal-based alloys, but is rarely observed in inorganic semiconductors and ceramic insulators. In particular, room-temperature ductile inorganic semiconductors were not known until now. Here, we report an inorganic alpha-Ag2S semiconductor that exhibits extraordinary metal-like ductility with high plastic deformation strains at room temperature. Analysis of the chemical bonding reveals systems of planes with relatively weak atomic interactions in the crystal structure. In combination with irregularly distributed silver-silver and sulfur-silver bonds due to the silver diffusion, they suppress the cleavage of the material, and thus result in unprecedented ductility. This work opens up the possibility of searching for ductile inorganic semiconductors/ceramics for flexible electronic devices.
收录类别SCI ; SCIE ; EI
语种英语
资助项目Shanghai Government[15JC1400301] ; Shanghai Government[16XD1403900]
WOS研究方向Chemistry ; Materials Science ; Physics
WOS类目Chemistry, Physical ; Materials Science, Multidisciplinary ; Physics, Applied ; Physics, Condensed Matter
WOS记录号WOS:000430942800018
出版者NATURE PUBLISHING GROUP
EI入藏号20181505002018
EI主题词Chemical analysis ; Chemical bonds ; Crystal atomic structure ; Ductility ; Silver compounds
WOS关键词ELECTRON LOCALIZABILITY ; HIGH-STRENGTH ; DEFORMATION ; BEHAVIOR ; METALS ; DISLOCATION ; CRYSTALS ; TITANIUM ; TI3SIC2 ; COPPER
原始文献类型Article
引用统计
被引频次:345[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符https://kms.shanghaitech.edu.cn/handle/2MSLDSTB/20206
专题物质科学与技术学院
物质科学与技术学院_特聘教授组_陈立东组
物质科学与技术学院_博士生
通讯作者Shi, Xun; Grin, Yuri; Chen, Lidong
作者单位
1.Chinese Acad Sci, Shanghai Inst Ceram, State Key Lab High Performance Ceram & Superfine, Shanghai, Peoples R China
2.Shanghai Tech Univ, Shanghai, Peoples R China
3.Univ Chinese Acad Sci, Beijing, Peoples R China
4.Max Planck Inst Chem Phys Fester Stoffe, Dresden, Germany
推荐引用方式
GB/T 7714
Shi, Xun,Chen, Hongyi,Hao, Feng,et al. Room-temperature ductile inorganic semiconductor[J]. NATURE MATERIALS,2018,17(5):421-+.
APA Shi, Xun.,Chen, Hongyi.,Hao, Feng.,Liu, Ruiheng.,Wang, Tuo.,...&Chen, Lidong.(2018).Room-temperature ductile inorganic semiconductor.NATURE MATERIALS,17(5),421-+.
MLA Shi, Xun,et al."Room-temperature ductile inorganic semiconductor".NATURE MATERIALS 17.5(2018):421-+.
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