Palladium(0)-Catalyzed Intermolecular Asymmetric Allylic Dearomatization of Polycyclic Indoles

doi:10.1021/acs.orglett.7b03887

	Palladium(0)-Catalyzed Intermolecular Asymmetric Allylic Dearomatization of Polycyclic Indoles
	Gao, Run-Duo 1; Ding, Lu2 ; Zheng, Chao 1; Dai, Li-Xin 1; You, Shu-Li1,2
	2018-02-02
发表期刊	ORGANIC LETTERS (IF:4.9[JCR-2023],4.5[5-Year])
ISSN	1523-7060
卷号	20 期号:3 页码:748-751
发表状态	已发表
DOI	10.1021/acs.orglett.7b03887
摘要	An intermolecular Pd-catalyzed allylic dearomatization reaction of polycyclic indoles with substituted allylic carbonates was realized in the presence of a newly synthesized chiral phosphoramidite ligand. Various polycyclic indoline and indolenine derivatives were successfully synthesized in excellent yields (up to 99%) with excellent enantioselectivity (up to 98% ee). The obtained products could undergo versatile transformations, increasing the application potential of the method in organic synthesis.
收录类别	SCI ; SCIE ; IC ; CCR
语种	英语
资助项目	Chinese Academy of Sciences[XDB20000000] ; Chinese Academy of Sciences[QYZDY-SSW-SLH012]
WOS研究方向	Chemistry
WOS类目	Chemistry, Organic
WOS记录号	WOS:000424729800064
出版者	AMER CHEMICAL SOC
WOS关键词	RING-OPENING CASCADE ; ENANTIOSELECTIVE SYNTHESIS ; ALPHA-ALLYLATION ; PROPARGYLIC DEAROMATIZATION ; ARYLATIVE DEAROMATIZATION ; CATALYZED DEAROMATIZATION ; SPIROCYCLIC INDOLENINES ; TRYPTAMINE DERIVATIVES ; CYCLOADDITION REACTION ; 3-SUBSTITUTED INDOLES
原始文献类型	Article
引用统计	正在获取...
文献类型	期刊论文
条目标识符	https://kms.shanghaitech.edu.cn/handle/2MSLDSTB/18299
专题	物质科学与技术学院物质科学与技术学院_特聘教授组_游书力组物质科学与技术学院_博士生
通讯作者	You, Shu-Li
作者单位	1.Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, 345 Lingling Lu, Shanghai 200032, Peoples R China 2.ShanghaiTech Univ, Sch Phys Sci & Technol, 100 Haike Rd, Shanghai 201210, Peoples R China
通讯作者单位	物质科学与技术学院
推荐引用方式 GB/T 7714	Gao, Run-Duo,Ding, Lu,Zheng, Chao,et al. Palladium(0)-Catalyzed Intermolecular Asymmetric Allylic Dearomatization of Polycyclic Indoles[J]. ORGANIC LETTERS,2018,20(3):748-751.
APA	Gao, Run-Duo,Ding, Lu,Zheng, Chao,Dai, Li-Xin,&You, Shu-Li.(2018).Palladium(0)-Catalyzed Intermolecular Asymmetric Allylic Dearomatization of Polycyclic Indoles.ORGANIC LETTERS,20(3),748-751.
MLA	Gao, Run-Duo,et al."Palladium(0)-Catalyzed Intermolecular Asymmetric Allylic Dearomatization of Polycyclic Indoles".ORGANIC LETTERS 20.3(2018):748-751.