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ShanghaiTech University Knowledge Management System
Cobalt-Catalyzed Carbonylation of C(sp(2))-H Bonds with Azodicarboxylate as the Carbonyl Source | |
2016-11-18 | |
发表期刊 | ORGANIC LETTERS (IF:4.9[JCR-2023],4.5[5-Year]) |
ISSN | 1523-7060 |
卷号 | 18期号:22页码:5960-5963 |
发表状态 | 已发表 |
DOI | 10.1021/acs.orglett.6b03111 |
摘要 | A novel and efficient approach for the C(sp(2))-H bond carbonylation of benzamides has been developed using stable and inexpensive Co(OAc)(2).4H(2)O as the catalyst and the commercially available and easily handling azodicarboxylates as the nontoxic carbonyl source. A broad range of substrates bearing diverse functional groups were tolerated. This is the first example where cobalt-catalyzed C(sp(2))-H bond carbonylation occurs with azodicarboxylate as the carbonyl source. |
收录类别 | SCI ; IC ; CCR |
语种 | 英语 |
资助项目 | Program of Shanghai Subject Chief Scientist[16XD1404600] |
WOS研究方向 | Chemistry |
WOS类目 | Chemistry, Organic |
WOS记录号 | WOS:000388428600048 |
出版者 | AMER CHEMICAL SOC |
WOS关键词 | C-H BOND ; DIETHYL AZODICARBOXYLATE ; ROOM-TEMPERATURE ; TERMINAL ALKYNES ; ACTIVATION ; AMIDES ; FUNCTIONALIZATION ; ANNULATION ; AMINATION ; ACCESS |
原始文献类型 | Article |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | https://kms.shanghaitech.edu.cn/handle/2MSLDSTB/1635 |
专题 | 生命科学与技术学院 生命科学与技术学院_特聘教授组_张翱组 生命科学与技术学院_博士生 |
通讯作者 | Zhang, Ao |
作者单位 | 1.Chinese Acad Sci, Shanghai Inst Mat Med, CAS Key Lab Receptor Res, Shanghai 201203, Peoples R China 2.Chinese Acad Sci, Shanghai Inst Mat Med, Synthet Organ & Med Chem Lab, Shanghai 201203, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 4.ShanghaiTech Univ, Shanghai 20120, Peoples R China |
通讯作者单位 | 上海科技大学 |
推荐引用方式 GB/T 7714 | Ni, Jiabin,Li, Jie,Fan, Zhoulong,et al. Cobalt-Catalyzed Carbonylation of C(sp(2))-H Bonds with Azodicarboxylate as the Carbonyl Source[J]. ORGANIC LETTERS,2016,18(22):5960-5963. |
APA | Ni, Jiabin,Li, Jie,Fan, Zhoulong,&Zhang, Ao.(2016).Cobalt-Catalyzed Carbonylation of C(sp(2))-H Bonds with Azodicarboxylate as the Carbonyl Source.ORGANIC LETTERS,18(22),5960-5963. |
MLA | Ni, Jiabin,et al."Cobalt-Catalyzed Carbonylation of C(sp(2))-H Bonds with Azodicarboxylate as the Carbonyl Source".ORGANIC LETTERS 18.22(2016):5960-5963. |
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