Disulfide-Catalyzed Visible-Light-Mediated Oxidative Cleavage of C=C Bonds and Evidence of an Olefin-Disulfide Charge-Transfer Complex

doi:10.1002/anie.201607948

	Disulfide-Catalyzed Visible-Light-Mediated Oxidative Cleavage of C=C Bonds and Evidence of an Olefin-Disulfide Charge-Transfer Complex
	Deng, Yuchao1,2,3 ; Wei, Xiao-Jing 4; Wang, Hui 1; Sun, Yuhan1,2 ; Noel, Timothy 4; Wang, Xiao 1,5,6
	2017-01-16
发表期刊	ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (IF:16.1[JCR-2023],16.2[5-Year])
ISSN	1433-7851
卷号	56 期号:3 页码:832-836
发表状态	已发表
DOI	10.1002/anie.201607948
摘要	A photocatalytic method for the aerobic oxidative cleavage of C=C bonds has been developed. Electron-rich aromatic disulfides were employed as photocatalyst. Upon visible-light irradiation, typical mono- and multi-substituted aromatic olefins could be converted into ketones and aldehydes at ambient temperature. Experimental and computational studies suggest that a disulfide-olefin charge-transfer complex is possibly responsible for the unconventional dissociation of S-S bond under visible light.
关键词	disulfide catalysts donor-acceptor complexes olefin oxidation organocatalysis visible-light photocatalysis
收录类别	SCI ; CCR ; EI
语种	英语
资助项目	European Union[641861]
WOS研究方向	Chemistry
WOS类目	Chemistry, Multidisciplinary
WOS记录号	WOS:000394996900028
出版者	WILEY-V C H VERLAG GMBH
EI入藏号	20165203168511
EI主题词	Aromatic compounds ; Catalysis ; Charge transfer ; Ketones ; Olefins ; Sulfur compounds
WOS关键词	COOXIDATION TOCO REACTION ; SUBSTITUTED BENZENETHIYL RADICALS ; GEM-DISUBSTITUTED ALKENES ; C DOUBLE-BOND ; MOLECULAR-OXYGEN ; FLASH-PHOTOLYSIS ; VINYL MONOMERS ; ADDITION RATES ; THIYL RADICALS ; ELECTRON-TRANSFER
原始文献类型	Article
引用统计	正在获取...
文献类型	期刊论文
条目标识符	https://kms.shanghaitech.edu.cn/handle/2MSLDSTB/1540
专题	物质科学与技术学院物质科学与技术学院_特聘教授组_孙予罕组物质科学与技术学院_博士生
通讯作者	Wang, Xiao
作者单位	1.Chinese Acad Sci, Shanghai Adv Res Inst, CAS Key Lab Low Carbon Convers Sci & Engn, 100 Haike Rd, Shanghai 201210, Peoples R China 2.ShanghaiTech Univ, Sch Phys Sci & Technol, Shanghai 201210, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 4.Eindhoven Univ Technol, Micro Flow Chem & Proc Technol, Dept Chem Engn & Chem, Den Dolech 2, NL-5612 AZ Eindhoven, Netherlands 5.Harvard Med Sch, Harvard NeuroDiscovery Ctr, 65 Landsdowne St, Cambridge, MA 02139 USA 6.Brigham & Womens Hosp, 65 Landsdowne St, Cambridge, MA 02139 USA
第一作者单位	物质科学与技术学院
推荐引用方式 GB/T 7714	Deng, Yuchao,Wei, Xiao-Jing,Wang, Hui,et al. Disulfide-Catalyzed Visible-Light-Mediated Oxidative Cleavage of C=C Bonds and Evidence of an Olefin-Disulfide Charge-Transfer Complex[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2017,56(3):832-836.
APA	Deng, Yuchao,Wei, Xiao-Jing,Wang, Hui,Sun, Yuhan,Noel, Timothy,&Wang, Xiao.(2017).Disulfide-Catalyzed Visible-Light-Mediated Oxidative Cleavage of C=C Bonds and Evidence of an Olefin-Disulfide Charge-Transfer Complex.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,56(3),832-836.
MLA	Deng, Yuchao,et al."Disulfide-Catalyzed Visible-Light-Mediated Oxidative Cleavage of C=C Bonds and Evidence of an Olefin-Disulfide Charge-Transfer Complex".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 56.3(2017):832-836.