Li/Li7La3Zr2O12/LiFePO4 All-Solid-State Battery with Ultrathin Nanoscale Solid Electrolyte
2017-01-26
发表期刊JOURNAL OF PHYSICAL CHEMISTRY C (IF:3.3[JCR-2023],3.5[5-Year])
ISSN1932-7447
卷号121期号:3页码:1431-1435
发表状态已发表
DOI10.1021/acs.jpcc.6b10268
摘要We introduced the nanoconcept in the oxide solid electrolyte Li7La3Zr2O12 (LLZO). All-solid-state Li/LiFePO4 (LFPO) cell using this solid electrolyte with thickness of several micrometers was assembled with appropriate solvent, dispersant, adhesives, and surfactant without cold- or hot-pressing. At room temperature, the Li/LLZO/LFPO cell showed the first discharge capacity of 160.4 mAh g(-1), which was 94.4% of the theoretical capacity of LFPO, and the cell provided a discharge capacity of 136.8 mAh g(-1) after 100 cycles. At 60 degrees C, the battery presented more stable electrochemical performance. The capacity loss during cycles 2-100 was only 0.06% (0.7 mAh g(-1)). The excellent performance could be attributed to the ultrathin solid electrolyte film.
收录类别SCI ; EI
语种英语
资助项目Ningbo 3315 International Team of Advanced Energy Storage Materials, Zhejiang Province Key Science and Technology Innovation Team[2013TD16]
WOS研究方向Chemistry ; Science & Technology - Other Topics ; Materials Science
WOS类目Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary
WOS记录号WOS:000393008900006
出版者AMER CHEMICAL SOC
EI入藏号20170503315677
EI主题词Electric batteries ; Electrolytes ; Hot pressing ; Lithium ; Lithium batteries ; Lithium compounds ; Solid state devices ; Thickness measurement
EI分类号Lithium and Alloys:542.4 ; Electric Batteries:702.1 ; Primary Batteries:702.1.1 ; Semiconductor Devices and Integrated Circuits:714.2 ; Chemical Agents and Basic Industrial Chemicals:803 ; Mechanical Variables Measurements:943.2
WOS关键词RECHARGEABLE LITHIUM BATTERIES ; LI7LA3ZR2O12 ELECTROLYTE ; CERAMIC ELECTROLYTES ; ION BATTERIES ; GARNET ; CONDUCTIVITY ; SUBSTITUTION ; FABRICATION ; STABILITY ; PHASE
原始文献类型Article
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文献类型期刊论文
条目标识符https://kms.shanghaitech.edu.cn/handle/2MSLDSTB/1528
专题物质科学与技术学院
物质科学与技术学院_特聘教授组_韩伟强组
物质科学与技术学院_特聘教授组_温兆银组
物质科学与技术学院_博士生
通讯作者Han, Weiqang
作者单位
1.Chinese Acad Sci, Ningbo Inst Ind Technol, Ningbo 315200, Zhejiang, Peoples R China
2.ShanghaiTech Univ, Sch Phys Sci & Technol, Shanghai 201210, Peoples R China
3.Zhejiang Univ, Dept Mat Sci & Engn, Hangzhou 310027, Zhejiang, Peoples R China
4.Chinese Acad Sci, Shanghai Inst Ceram, Shanghai 200050, Peoples R China
5.Univ Chinese Acad Sci, Coll Mat Sci & Optoelect Technol, Beijing 100049, Peoples R China
第一作者单位物质科学与技术学院
通讯作者单位物质科学与技术学院
推荐引用方式
GB/T 7714
Yan, Xufeng,Li, Zhuobin,Wen, Zhaoyin,et al. Li/Li7La3Zr2O12/LiFePO4 All-Solid-State Battery with Ultrathin Nanoscale Solid Electrolyte[J]. JOURNAL OF PHYSICAL CHEMISTRY C,2017,121(3):1431-1435.
APA Yan, Xufeng,Li, Zhuobin,Wen, Zhaoyin,&Han, Weiqang.(2017).Li/Li7La3Zr2O12/LiFePO4 All-Solid-State Battery with Ultrathin Nanoscale Solid Electrolyte.JOURNAL OF PHYSICAL CHEMISTRY C,121(3),1431-1435.
MLA Yan, Xufeng,et al."Li/Li7La3Zr2O12/LiFePO4 All-Solid-State Battery with Ultrathin Nanoscale Solid Electrolyte".JOURNAL OF PHYSICAL CHEMISTRY C 121.3(2017):1431-1435.
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