Potential-dependent C-C coupling mechanism and activity of C-2 formation in the electrocatalytic reduction of CO2 on defective Cu(100) surfaces

doi:10.1039/d1cc06735d

	Potential-dependent C-C coupling mechanism and activity of C-2 formation in the electrocatalytic reduction of CO2 on defective Cu(100) surfaces
	Liu, Hong; Yang, Bo
	2022-01-16
发表期刊	CHEMICAL COMMUNICATIONS (IF:4.3[JCR-2023],4.4[5-Year])
ISSN	1359-7345
EISSN	1364-548X
发表状态	已发表
DOI	10.1039/d1cc06735d
摘要	The potential-dependent C-C coupling mechanism for C-2 formation in the electrocatalytic reduction of CO2 is studied on several defective Cu(100) surfaces, and a nonmonotonic trend is observed between the effective free energy barriers and the average coordination numbers. Further structural analysis reveals that Cu surface strain along the parallel and vertical directions with respect to the C-C bond would have distinct impacts on the modulation of the barriers.
URL	查看原文
收录类别	SCI ; SCIE ; EI
语种	英语
资助项目	National Natural Science Foundation of China[21991152,21991150] ; Shanghai Rising-Star Program[20QA1406800]
WOS研究方向	Chemistry
WOS类目	Chemistry, Multidisciplinary
WOS记录号	WOS:000732005000001
出版者	ROYAL SOC CHEMISTRY
引用统计	正在获取...
文献类型	期刊论文
条目标识符	https://kms.shanghaitech.edu.cn/handle/2MSLDSTB/138711
专题	物质科学与技术学院_博士生物质科学与技术学院_PI研究组_杨波组
通讯作者	Yang, Bo
作者单位	Shanghai Tech Univ, Sch Phys Sci & Technol, Shanghai 201210, Peoples R China
第一作者单位	物质科学与技术学院
通讯作者单位	物质科学与技术学院
第一作者的第一单位	物质科学与技术学院
推荐引用方式 GB/T 7714	Liu, Hong,Yang, Bo. Potential-dependent C-C coupling mechanism and activity of C-2 formation in the electrocatalytic reduction of CO2 on defective Cu(100) surfaces[J]. CHEMICAL COMMUNICATIONS,2022.
APA	Liu, Hong,&Yang, Bo.(2022).Potential-dependent C-C coupling mechanism and activity of C-2 formation in the electrocatalytic reduction of CO2 on defective Cu(100) surfaces.CHEMICAL COMMUNICATIONS.
MLA	Liu, Hong,et al."Potential-dependent C-C coupling mechanism and activity of C-2 formation in the electrocatalytic reduction of CO2 on defective Cu(100) surfaces".CHEMICAL COMMUNICATIONS (2022).