Ni Hollow Fiber Encapsulated Bi@Zeolite for Efficient CO2 Electroreduction
2021-09-27
发表期刊ACS APPLIED ENERGY MATERIALS (IF:5.4[JCR-2023],5.9[5-Year])
ISSN2574-0962
卷号4期号:9页码:8933-8940
发表状态已发表
DOI10.1021/acsaem.1c01195
摘要

CO2 electroreduction has attracted considerable investigations due to the desirable coupling of renewable energy utilization and value-added chemical production. However, it encounters the bottlenecks of high energy barrier and low efficiency owing to the limited CO2 solubility and mass transfer. Herein, a porous Ni hollow fiber encapsulated Bi@Zeolite catalyst was developed as a self-standing gas diffusion electrode for efficient CO2 reduction to CO. Such a delicate electrode configuration reinforces CO2 adsorption/activation on Bi@Zeolite active sites and favors mass transfer due to a shortened and directed diffusion path. These synergetic promotions induced by Bi@Zeolite encapsulated in Ni hollow fiber achieved a high CO Faradaic efficiency of 74.1% at only an overpotential of 260 mV in the ionic-liquid based electrolyte, which was 2.6 times that on the Ni foil planar configuration. In addition, both CO Faradaic efficiency and current density remained almost constant for the duration of a 16 h test, further indicating the superiority of the Ni hollow fiber encapsulated configuration. This work demonstrates the potential of using a hollow fiber to reinforce reaction kinetics for efficient CO2 electroreduction.

关键词CO2 electroreduction Hollow fiber encapsulation Ionic liquid Bismuth Zeolite
收录类别SCIE ; EI
语种英语
WOS研究方向Chemistry ; Energy & Fuels ; Materials Science
WOS类目Chemistry, Physical ; Energy & Fuels ; Materials Science, Multidisciplinary
WOS记录号WOS:000703338600028
出版者AMER CHEMICAL SOC
原始文献类型Article
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文献类型期刊论文
条目标识符https://kms.shanghaitech.edu.cn/handle/2MSLDSTB/128525
专题物质科学与技术学院_博士生
物质科学与技术学院_特聘教授组_孙予罕组
物质科学与技术学院_特聘教授组_魏伟组
通讯作者Chen, Wei; Wei, Wei; Sun, Yuhan
作者单位
1.Chinese Acad Sci, CAS Key Lab Low Carbon Convers Sci & Engn, Shanghai Adv Res Inst, Shanghai 201210, Peoples R China;
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China;
3.Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai 201210, Peoples R China;
4.Chinese Acad Sci, Shanghai Adv Res Inst, Zhangjiang Lab, Shanghai Synchrotron Radiat Facil, Shanghai 201204, Peoples R China;
5.Shanghai Univ, Coll Mat Sci & Engn, Shanghai 200444, Peoples R China;
6.ShanghaiTech Univ, Sch Phys Sci & Technol, Shanghai 201210, Peoples R China
通讯作者单位物质科学与技术学院
推荐引用方式
GB/T 7714
Zhao, Xiaoju,Song, Yanfang,Yang, Shuai,et al. Ni Hollow Fiber Encapsulated Bi@Zeolite for Efficient CO2 Electroreduction[J]. ACS APPLIED ENERGY MATERIALS,2021,4(9):8933-8940.
APA Zhao, Xiaoju.,Song, Yanfang.,Yang, Shuai.,Chen, Wei.,Li, Tong.,...&Sun, Yuhan.(2021).Ni Hollow Fiber Encapsulated Bi@Zeolite for Efficient CO2 Electroreduction.ACS APPLIED ENERGY MATERIALS,4(9),8933-8940.
MLA Zhao, Xiaoju,et al."Ni Hollow Fiber Encapsulated Bi@Zeolite for Efficient CO2 Electroreduction".ACS APPLIED ENERGY MATERIALS 4.9(2021):8933-8940.
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