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Ni Hollow Fiber Encapsulated Bi@Zeolite for Efficient CO2 Electroreduction | |
2021-09-27 | |
发表期刊 | ACS APPLIED ENERGY MATERIALS (IF:5.4[JCR-2023],5.9[5-Year]) |
ISSN | 2574-0962 |
卷号 | 4期号:9页码:8933-8940 |
发表状态 | 已发表 |
DOI | 10.1021/acsaem.1c01195 |
摘要 | CO2 electroreduction has attracted considerable investigations due to the desirable coupling of renewable energy utilization and value-added chemical production. However, it encounters the bottlenecks of high energy barrier and low efficiency owing to the limited CO2 solubility and mass transfer. Herein, a porous Ni hollow fiber encapsulated Bi@Zeolite catalyst was developed as a self-standing gas diffusion electrode for efficient CO2 reduction to CO. Such a delicate electrode configuration reinforces CO2 adsorption/activation on Bi@Zeolite active sites and favors mass transfer due to a shortened and directed diffusion path. These synergetic promotions induced by Bi@Zeolite encapsulated in Ni hollow fiber achieved a high CO Faradaic efficiency of 74.1% at only an overpotential of 260 mV in the ionic-liquid based electrolyte, which was 2.6 times that on the Ni foil planar configuration. In addition, both CO Faradaic efficiency and current density remained almost constant for the duration of a 16 h test, further indicating the superiority of the Ni hollow fiber encapsulated configuration. This work demonstrates the potential of using a hollow fiber to reinforce reaction kinetics for efficient CO2 electroreduction. |
关键词 | CO2 electroreduction Hollow fiber encapsulation Ionic liquid Bismuth Zeolite |
收录类别 | SCIE ; EI |
语种 | 英语 |
WOS研究方向 | Chemistry ; Energy & Fuels ; Materials Science |
WOS类目 | Chemistry, Physical ; Energy & Fuels ; Materials Science, Multidisciplinary |
WOS记录号 | WOS:000703338600028 |
出版者 | AMER CHEMICAL SOC |
原始文献类型 | Article |
引用统计 | 正在获取...
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文献类型 | 期刊论文 |
条目标识符 | https://kms.shanghaitech.edu.cn/handle/2MSLDSTB/128525 |
专题 | 物质科学与技术学院_博士生 物质科学与技术学院_特聘教授组_孙予罕组 物质科学与技术学院_特聘教授组_魏伟组 |
通讯作者 | Chen, Wei; Wei, Wei; Sun, Yuhan |
作者单位 | 1.Chinese Acad Sci, CAS Key Lab Low Carbon Convers Sci & Engn, Shanghai Adv Res Inst, Shanghai 201210, Peoples R China; 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China; 3.Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai 201210, Peoples R China; 4.Chinese Acad Sci, Shanghai Adv Res Inst, Zhangjiang Lab, Shanghai Synchrotron Radiat Facil, Shanghai 201204, Peoples R China; 5.Shanghai Univ, Coll Mat Sci & Engn, Shanghai 200444, Peoples R China; 6.ShanghaiTech Univ, Sch Phys Sci & Technol, Shanghai 201210, Peoples R China |
通讯作者单位 | 物质科学与技术学院 |
推荐引用方式 GB/T 7714 | Zhao, Xiaoju,Song, Yanfang,Yang, Shuai,et al. Ni Hollow Fiber Encapsulated Bi@Zeolite for Efficient CO2 Electroreduction[J]. ACS APPLIED ENERGY MATERIALS,2021,4(9):8933-8940. |
APA | Zhao, Xiaoju.,Song, Yanfang.,Yang, Shuai.,Chen, Wei.,Li, Tong.,...&Sun, Yuhan.(2021).Ni Hollow Fiber Encapsulated Bi@Zeolite for Efficient CO2 Electroreduction.ACS APPLIED ENERGY MATERIALS,4(9),8933-8940. |
MLA | Zhao, Xiaoju,et al."Ni Hollow Fiber Encapsulated Bi@Zeolite for Efficient CO2 Electroreduction".ACS APPLIED ENERGY MATERIALS 4.9(2021):8933-8940. |
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