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ShanghaiTech University Knowledge Management System
Alkoxy Radicals See the Light: New Paradigms of Photochemical Synthesis | |
2022-01-26 | |
发表期刊 | CHEMICAL REVIEWS (IF:51.4[JCR-2023],63.5[5-Year]) |
ISSN | 0009-2665 |
EISSN | 1520-6890 |
卷号 | 122期号:2 |
发表状态 | 已发表 |
DOI | 10.1021/acs.chemrev.1c00256 |
摘要 | Alkoxy radicals are highly reactive species that have long been recognized as versatile intermediates in organic synthesis. However, their development has long been impeded due to a lack of convenient methods for their generation. Thanks to advances in photoredox catalysis, enabling facile access to alkoxy radicals from bench-stable precursors and free alcohols under mild conditions, research interest in this field has been renewed. This review comprehensively summarizes the recent progress in alkoxy radical-mediated transformations under visible light irradiation. Elementary steps for alkoxy radical generation from either radical precursors or free alcohols are central to reaction development; thus, each section is categorized and discussed accordingly. Throughout this review, we have focused on the different mechanisms of alkoxy radical generation as well as their impact on synthetic utilizations. Notably, the catalytic generation of alkoxy radicals from abundant alcohols is still in the early stage, providing intriguing opportunities to exploit alkoxy radicals for diverse synthetic paradigms. |
URL | 查看原文 |
收录类别 | SCI ; SCIE ; EI |
语种 | 英语 |
资助项目 | National Natural Science Foundation of China[21772121,21971163] |
WOS研究方向 | Chemistry |
WOS类目 | Chemistry, Multidisciplinary |
WOS记录号 | WOS:000765830800014 |
出版者 | AMER CHEMICAL SOC |
引用统计 | 正在获取...
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文献类型 | 期刊论文 |
条目标识符 | https://kms.shanghaitech.edu.cn/handle/2MSLDSTB/128268 |
专题 | 物质科学与技术学院_博士生 |
通讯作者 | Zuo, Zhiwei |
作者单位 | 1.Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China 2.Nanjing Univ Chinese Med, Sch Pharm, Nanjing 210023, Peoples R China 3.ShanghaiTech Univ, Sch Phys Sci & Technol, Shanghai 201210, Peoples R China |
推荐引用方式 GB/T 7714 | Chang, Liang,An, Qing,Duan, Lingfei,et al. Alkoxy Radicals See the Light: New Paradigms of Photochemical Synthesis[J]. CHEMICAL REVIEWS,2022,122(2). |
APA | Chang, Liang,An, Qing,Duan, Lingfei,Feng, Kaixuan,&Zuo, Zhiwei.(2022).Alkoxy Radicals See the Light: New Paradigms of Photochemical Synthesis.CHEMICAL REVIEWS,122(2). |
MLA | Chang, Liang,et al."Alkoxy Radicals See the Light: New Paradigms of Photochemical Synthesis".CHEMICAL REVIEWS 122.2(2022). |
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