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Alkoxy Radicals See the Light: New Paradigms of Photochemical Synthesis
2022-01-26
发表期刊CHEMICAL REVIEWS (IF:51.4[JCR-2023],63.5[5-Year])
ISSN0009-2665
EISSN1520-6890
卷号122期号:2
发表状态已发表
DOI10.1021/acs.chemrev.1c00256
摘要

Alkoxy radicals are highly reactive species that have long been recognized as versatile intermediates in organic synthesis. However, their development has long been impeded due to a lack of convenient methods for their generation. Thanks to advances in photoredox catalysis, enabling facile access to alkoxy radicals from bench-stable precursors and free alcohols under mild conditions, research interest in this field has been renewed. This review comprehensively summarizes the recent progress in alkoxy radical-mediated transformations under visible light irradiation. Elementary steps for alkoxy radical generation from either radical precursors or free alcohols are central to reaction development; thus, each section is categorized and discussed accordingly. Throughout this review, we have focused on the different mechanisms of alkoxy radical generation as well as their impact on synthetic utilizations. Notably, the catalytic generation of alkoxy radicals from abundant alcohols is still in the early stage, providing intriguing opportunities to exploit alkoxy radicals for diverse synthetic paradigms.

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收录类别SCI ; SCIE ; EI
语种英语
资助项目National Natural Science Foundation of China[21772121,21971163]
WOS研究方向Chemistry
WOS类目Chemistry, Multidisciplinary
WOS记录号WOS:000765830800014
出版者AMER CHEMICAL SOC
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文献类型期刊论文
条目标识符https://kms.shanghaitech.edu.cn/handle/2MSLDSTB/128268
专题物质科学与技术学院_博士生
通讯作者Zuo, Zhiwei
作者单位
1.Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China
2.Nanjing Univ Chinese Med, Sch Pharm, Nanjing 210023, Peoples R China
3.ShanghaiTech Univ, Sch Phys Sci & Technol, Shanghai 201210, Peoples R China
推荐引用方式
GB/T 7714
Chang, Liang,An, Qing,Duan, Lingfei,et al. Alkoxy Radicals See the Light: New Paradigms of Photochemical Synthesis[J]. CHEMICAL REVIEWS,2022,122(2).
APA Chang, Liang,An, Qing,Duan, Lingfei,Feng, Kaixuan,&Zuo, Zhiwei.(2022).Alkoxy Radicals See the Light: New Paradigms of Photochemical Synthesis.CHEMICAL REVIEWS,122(2).
MLA Chang, Liang,et al."Alkoxy Radicals See the Light: New Paradigms of Photochemical Synthesis".CHEMICAL REVIEWS 122.2(2022).
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