Application of Electron-Rich Covalent Organic Frameworks COF-JLU25 for Photocatalytic Aerobic Oxidative Hydroxylation of Arylboronic Acids to Phenols
Xiao, Guangju1,2,3; Li, Wenqian1,2; Chen, Tao1,2; Hu, Wei-Bo1,2; Yang, Hui1,2,3; Liu, Yahu A.4; Wen, Ke1,2,3
2021
Source PublicationEUROPEAN JOURNAL OF ORGANIC CHEMISTRY
ISSN1434-193X
EISSN1099-0690
Volume2021Issue:29Pages:3986-3991
Status已发表
DOI10.1002/ejoc.202100173
Abstract

Visible-light-driven organic reactions are environmentally friendly green chemical transformations among which photosynthetic oxidative hydroxylation of arylboronic acids to phenols has attracted increasing research interest during the very recent years. Given the efficiency and reusability of heterogeneous catalysts, COF-JLU25, an electron-rich COF-based photocatalyst constructed by integrating electron-donating blocks 1,3,6,8-tetrakis(4-aminophenyl)pyrene (PyTA) and 4-[4-(4-formylmethyl)-2,5-dimethoxyphenyl] benzaldehyde (TpDA), was selected as a photocatalyst for the oxidative hydroxylation of arylboronic acids. In our studies, COF-JLU25 demonstrated excellent photocatalytic activity with high efficiency, robust reusability, and low catalyst loading, showcasing an application potential of previously underexplored COF-based photocatalyst composed solely of electron-rich units.

KeywordArylboronic acids Covalent organic frameworks Oxidative hydroxylation Photocatalysis Superoxide radical
Indexed BySCIE
Language英语
WOS Research AreaChemistry
WOS SubjectChemistry, Organic
WOS IDWOS:000632317800001
PublisherWILEY-V C H VERLAG GMBH
Original Document TypeArticle
Citation statistics
Cited Times [WOS]:0   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttps://kms.shanghaitech.edu.cn/handle/2MSLDSTB/126153
Collection物质科学与技术学院_特聘教授组_杨辉组
物质科学与技术学院_特聘教授组_文珂组
物质科学与技术学院_博士生
Affiliation1.Chinese Acad Sci Shanghai, Shanghai Adv Res Inst, Shanghai, Peoples R China;
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China;
3.ShanghaiTech Univ, Sch Phys Sci & Technol, Shanghai 201210, Peoples R China;
4.ChemBridge Res Labs, Med Chem, San Diego, CA 92127 USA
First Author AffilicationSchool of Physical Science and Technology
Recommended Citation
GB/T 7714
Xiao, Guangju,Li, Wenqian,Chen, Tao,et al. Application of Electron-Rich Covalent Organic Frameworks COF-JLU25 for Photocatalytic Aerobic Oxidative Hydroxylation of Arylboronic Acids to Phenols[J]. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY,2021,2021(29):3986-3991.
APA Xiao, Guangju.,Li, Wenqian.,Chen, Tao.,Hu, Wei-Bo.,Yang, Hui.,...&Wen, Ke.(2021).Application of Electron-Rich Covalent Organic Frameworks COF-JLU25 for Photocatalytic Aerobic Oxidative Hydroxylation of Arylboronic Acids to Phenols.EUROPEAN JOURNAL OF ORGANIC CHEMISTRY,2021(29),3986-3991.
MLA Xiao, Guangju,et al."Application of Electron-Rich Covalent Organic Frameworks COF-JLU25 for Photocatalytic Aerobic Oxidative Hydroxylation of Arylboronic Acids to Phenols".EUROPEAN JOURNAL OF ORGANIC CHEMISTRY 2021.29(2021):3986-3991.
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