HPM-14: A New Germanosilicate Zeolite with Interconnected Extra-Large Pores Plus Odd-Membered and Small Pores**

doi:10.1002/anie.202011801

KMS > 物质科学与技术学院 > PI研究组 > Osamu Terasaki组

	HPM-14: A New Germanosilicate Zeolite with Interconnected Extra-Large Pores Plus Odd-Membered and Small Pores**
	Gao, Zihao Rei 1; Li, Jian 2; Lin, Cong 3,4; Mayoral, Alvaro5,6,7 ; Sun, Junliang 3; Camblor, Miguel A.1
	2021-02-15
发表期刊	ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
ISSN	1433-7851
发表状态	已发表
DOI	10.1002/anie.202011801
摘要	HPM-14 is a new extra-large pore zeolite synthesized using imidazolium-based organic structure-directing agents (SDAs), fluoride anions, and germanium and silicon as tetrahedral components of the framework. Owing to the presence of stacking disorder, the structure elucidation of HPM-14 was challenging, and different techniques were necessary to clarify the details of the structure and to understand the nature of the disorder. The structure has been solved by three-dimensional electron-diffraction technique (3D ED) and consists of an intergrowth of two polymorphs possessing a three-dimensional channel system, including an extra-large pore opened through windows made up of sixteen tetrahedral atoms (16-membered ring, 16MR) as well as two additional sets of odd-membered (9MR) and small (8MR) pores. The intergrowth has been studied by scanning transmission electron microscopy (C-s-STEM) and powder X-ray diffraction simulations (DIFFaX), which show a large predominance of the monoclinic polymorph A.
关键词	extra-large pores stacking faults structure solution three-dimensional electron diffraction zeolites
URL	查看原文
收录类别	SCI ; EI ; SCIE
语种	英语
资助项目	Spanish Ministry of Science, Innovation and Universities[MAT2015-71117-R][PID2019-105479RB-I00] ; National Natural Science Foundation of China[21871009][21621061][21527803][21471009][NFSC-21850410448][NSFC-21835002] ; Centre for High-resolution Electron Microscopy (ChEM) - SPST of ShanghaiTech University[EM02161943] ; Spanish Ministry of Science, Innovation and Universities through the Ramon y Cajal Program[RYC2018-024561-I]
WOS研究方向	Chemistry
WOS类目	Chemistry, Multidisciplinary
WOS记录号	WOS:000598269100001
出版者	WILEY-V C H VERLAG GMBH
引用统计
文献类型	期刊论文
条目标识符	https://kms.shanghaitech.edu.cn/handle/2MSLDSTB/124895
专题	物质科学与技术学院_PI研究组_Osamu Terasaki组
通讯作者	Li, Jian; Camblor, Miguel A.
作者单位	1.Consejo Super Invest Cient ICMM CSIC, Inst Ciencia Mat Madrid, C Sor Juana Ines de la Cruz 3, Madrid 28049, Spain 2.Stockholm Univ, Berzelii Ctr EXSELENT Porous Mat, Dept Mat & Environm Chem, S-10691 Stockholm, Sweden 3.Peking Univ, Coll Chem & Mol Engn, Beijing Natl Lab Mol Sci, 5 Yiheyuan Rd, Beijing 100871, Peoples R China 4.Peking Univ, Sch Adv Mat, Shenzhen Grad Sch, Shenzhen 518055, Peoples R China 5.Univ Zaragoza, Inst Nanociencia & Mat Aragon INMA CSIC, 12 Calle Pedro Cerbuna, Zaragoza 50009, Spain 6.Univ Zaragoza, Lab Microscopias Avanzadas LMA, Zaragoza 50018, Spain 7.ShanghaiTech Univ, Ctr High Resolut Electron Microscopy ChEM, Sch Phys Sci & Technol, 393 Middle Huaxia Rd, Shanghai 201210, Peoples R China
推荐引用方式 GB/T 7714	Gao, Zihao Rei,Li, Jian,Lin, Cong,et al. HPM-14: A New Germanosilicate Zeolite with Interconnected Extra-Large Pores Plus Odd-Membered and Small Pores**[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2021.
APA	Gao, Zihao Rei,Li, Jian,Lin, Cong,Mayoral, Alvaro,Sun, Junliang,&Camblor, Miguel A..(2021).HPM-14: A New Germanosilicate Zeolite with Interconnected Extra-Large Pores Plus Odd-Membered and Small Pores**.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION.
MLA	Gao, Zihao Rei,et al."HPM-14: A New Germanosilicate Zeolite with Interconnected Extra-Large Pores Plus Odd-Membered and Small Pores**".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021).