Construction of Spironaphthalenones via Gold-Catalyzed Intramolecular Dearomatization Reaction of beta-Naphthol Derivatives

doi:10.1021/acs.orglett.0c01945

	Construction of Spironaphthalenones via Gold-Catalyzed Intramolecular Dearomatization Reaction of beta-Naphthol Derivatives
	Ding, Lu1,2 ; Wu, Wen-Ting 1; Zhang, Liming 3; You, Shu-Li1,2
	2020-08-07
发表期刊	ORGANIC LETTERS (IF:4.9[JCR-2023],4.5[5-Year])
ISSN	1523-7060
EISSN	1523-7052
卷号	22 期号:15 页码:5861-5865
发表状态	已发表
DOI	10.1021/acs.orglett.0c01945
摘要	A gold-catalyzed dearomatization reaction of beta-naphthol derivatives via intramolecular hydroalkylation of alkynes is described. In the presence of 5 mol % Au complex, various spironaphthalenones were obtained from alpha-tethered alkyne beta-naphthols in good to excellent yields (76-99%) under open-flask conditions.
收录类别	SCI ; SCIE ; IC ; CCR
资助项目	National Key R&D Program of China[2016YFA0202900] ; NSFC[21821002][91856201][21961132002] ; CAS[XDB20000000][QYZDY-SSW-SLH012]
WOS研究方向	Chemistry
WOS类目	Chemistry, Organic
WOS记录号	WOS:000562077400029
出版者	AMER CHEMICAL SOC
WOS关键词	ASYMMETRIC ALLYLIC ETHERIFICATION ; NATURAL-PRODUCTS ; PHENOL ; ARYL ; SPIROCYCLIZATION ; ALKYLATION ; CARBENES ; LIGANDS ; CYCLIZATION ; COMPLEXES
原始文献类型	Article
引用统计	正在获取...
文献类型	期刊论文
条目标识符	https://kms.shanghaitech.edu.cn/handle/2MSLDSTB/123089
专题	物质科学与技术学院_博士生物质科学与技术学院_特聘教授组_游书力组
通讯作者	Zhang, Liming; You, Shu-Li
作者单位	1.Chinese Acad Sci, Ctr Excellence Mol Synth, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China 2.ShanghaiTech Univ, Sch Phys Sci & Technol, Shanghai 201210, Peoples R China 3.Univ Calif Santa Barbara, Dept Chem & Biochem, Santa Barbara, CA 93106 USA
第一作者单位	物质科学与技术学院
通讯作者单位	物质科学与技术学院
推荐引用方式 GB/T 7714	Ding, Lu,Wu, Wen-Ting,Zhang, Liming,et al. Construction of Spironaphthalenones via Gold-Catalyzed Intramolecular Dearomatization Reaction of beta-Naphthol Derivatives[J]. ORGANIC LETTERS,2020,22(15):5861-5865.
APA	Ding, Lu,Wu, Wen-Ting,Zhang, Liming,&You, Shu-Li.(2020).Construction of Spironaphthalenones via Gold-Catalyzed Intramolecular Dearomatization Reaction of beta-Naphthol Derivatives.ORGANIC LETTERS,22(15),5861-5865.
MLA	Ding, Lu,et al."Construction of Spironaphthalenones via Gold-Catalyzed Intramolecular Dearomatization Reaction of beta-Naphthol Derivatives".ORGANIC LETTERS 22.15(2020):5861-5865.