Direct enantioselective Mannich reactions of alpha-azido cyclic ketones: asymmetric construction of chiral azides possessing an alpha-quaternary stereocenter

doi:10.1039/c9cc08000g

	Direct enantioselective Mannich reactions of alpha-azido cyclic ketones: asymmetric construction of chiral azides possessing an alpha-quaternary stereocenter
	Ye, Xueqian1,2 ; Pan, Yongkai 1; Yang, Xiaoyu1
	2020-01-04
发表期刊	CHEMICAL COMMUNICATIONS (IF:4.3[JCR-2023],4.4[5-Year])
ISSN	1359-7345
EISSN	1364-548X
卷号	56 期号:1 页码:98-101
发表状态	已发表
DOI	10.1039/c9cc08000g
摘要	Direct enantioselective Mannich reactions of alpha-azido cyclic ketones with aldimines are realized through chiral phosphoric acid catalysis, which generate chiral azides possessing an alpha-quanternary stereocenter with complete regioselectivities and high diastereoselectivities and enantioselectivities.
收录类别	SCI ; SCIE ; IC ; CCR
语种	英语
资助项目	NSFC[21702138]
WOS研究方向	Chemistry
WOS类目	Chemistry, Multidisciplinary
WOS记录号	WOS:000503187300012
出版者	ROYAL SOC CHEMISTRY
WOS关键词	BRONSTED ACID ; KINETIC RESOLUTION ; MESO-AZIRIDINES ; ORGANIC AZIDES ; ALDOL REACTION ; DESYMMETRIZATION ; CYCLOADDITION ; CATALYSIS ; AZIDATION
原始文献类型	Article
引用统计	正在获取...
文献类型	期刊论文
条目标识符	https://kms.shanghaitech.edu.cn/handle/2MSLDSTB/104973
专题	物质科学与技术学院_硕士生物质科学与技术学院_PI研究组_杨晓瑜组
通讯作者	Yang, Xiaoyu
作者单位	1.ShanghaiTech Univ, Sch Phys Sci & Technol, Shanghai 201210, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
第一作者单位	物质科学与技术学院
通讯作者单位	物质科学与技术学院
第一作者的第一单位	物质科学与技术学院
推荐引用方式 GB/T 7714	Ye, Xueqian,Pan, Yongkai,Yang, Xiaoyu. Direct enantioselective Mannich reactions of alpha-azido cyclic ketones: asymmetric construction of chiral azides possessing an alpha-quaternary stereocenter[J]. CHEMICAL COMMUNICATIONS,2020,56(1):98-101.
APA	Ye, Xueqian,Pan, Yongkai,&Yang, Xiaoyu.(2020).Direct enantioselective Mannich reactions of alpha-azido cyclic ketones: asymmetric construction of chiral azides possessing an alpha-quaternary stereocenter.CHEMICAL COMMUNICATIONS,56(1),98-101.
MLA	Ye, Xueqian,et al."Direct enantioselective Mannich reactions of alpha-azido cyclic ketones: asymmetric construction of chiral azides possessing an alpha-quaternary stereocenter".CHEMICAL COMMUNICATIONS 56.1(2020):98-101.