Rhodium(III)-Catalyzed C-H Alkynylation of Ferrocenes with Hypervalent Iodine Reagents

doi:10.1021/acs.joc.7b00775

	Rhodium(III)-Catalyzed C-H Alkynylation of Ferrocenes with Hypervalent Iodine Reagents
	Wang, Shao-Bo2 ; Gu, Qing 1; You, Shu-Li1,2
	2017-11-17
发表期刊	JOURNAL OF ORGANIC CHEMISTRY (IF:3.3[JCR-2023],3.2[5-Year])
ISSN	0022-3263
卷号	82 期号:22 页码:11829-11835
发表状态	已发表
DOI	10.1021/acs.joc.7b00775
摘要	Rapid access to mono- or dialkynylation of ferrocene with ethynylbenziodoxolones as the alkynylation reagents was achieved via rhodium-catalyzed direct C-H bond functionalization at room temperature. Mono- and dialkynylation were easily modulated by varying the sterical volume of the directing group, such as pyridine and isoquinoline, and amount of hypervalent iodine reagents. A wide range of ferrocene-based alkynylation products could be obtained in up to 94% yield, and a gram-scale reaction also proceeded smoothly with high efficiency.
收录类别	SCI ; IC ; CCR ; EI
语种	英语
资助项目	CAS[XDB20000000] ; CAS[QYZDY-SSW-SLH012]
WOS研究方向	Chemistry
WOS类目	Chemistry, Organic
WOS记录号	WOS:000416204400020
出版者	AMER CHEMICAL SOC
EI入藏号	20174704439088
EI主题词	Catalysis ; Iron compounds ; Organometallics ; Rhodium ; Rhodium compounds
EI分类号	Precious Metals:547.1 ; Chemical Reactions:802.2 ; Chemical Products Generally:804 ; Organic Compounds:804.1
WOS关键词	PLANAR-CHIRAL FERROCENES ; CATALYZED DIRECT ALKYNYLATION ; ENANTIOSELECTIVE SYNTHESIS ; MILD CONDITIONS ; CHELATION-ASSISTANCE ; ROOM-TEMPERATURE ; BOND ACTIVATION ; DEHYDROGENATIVE ANNULATION ; ETHYNYL BENZIODOXOLONES ; HIGHLY EFFICIENT
原始文献类型	Article
引用统计	正在获取...
文献类型	期刊论文
条目标识符	https://kms.shanghaitech.edu.cn/handle/2MSLDSTB/10044
专题	物质科学与技术学院物质科学与技术学院_特聘教授组_游书力组物质科学与技术学院_博士生
通讯作者	You, Shu-Li
作者单位	1.Univ Chinese Acad Sci, Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, 345 LinglingLu, Shanghai 200032, Peoples R China 2.ShanghaiTech Univ, Sch Phys Sci & Technol, 100 Haike Rd, Shanghai 201210, Peoples R China
第一作者单位	物质科学与技术学院
通讯作者单位	物质科学与技术学院
第一作者的第一单位	物质科学与技术学院
推荐引用方式 GB/T 7714	Wang, Shao-Bo,Gu, Qing,You, Shu-Li. Rhodium(III)-Catalyzed C-H Alkynylation of Ferrocenes with Hypervalent Iodine Reagents[J]. JOURNAL OF ORGANIC CHEMISTRY,2017,82(22):11829-11835.
APA	Wang, Shao-Bo,Gu, Qing,&You, Shu-Li.(2017).Rhodium(III)-Catalyzed C-H Alkynylation of Ferrocenes with Hypervalent Iodine Reagents.JOURNAL OF ORGANIC CHEMISTRY,82(22),11829-11835.
MLA	Wang, Shao-Bo,et al."Rhodium(III)-Catalyzed C-H Alkynylation of Ferrocenes with Hypervalent Iodine Reagents".JOURNAL OF ORGANIC CHEMISTRY 82.22(2017):11829-11835.