Palladium-Catalyzed C-H Diarylation of Ferrocenecarboxylic Acids with Aryl Iodides
Xiang, Jia-Chen1,2; Wu, Zhi-Jie1,3; Gu, Qing1; You, Shu-Li1,3
2019-10-18
Source PublicationJOURNAL OF ORGANIC CHEMISTRY
ISSN0022-3263
Volume84Issue:20Pages:13144-13149
DOI10.1021/acs.joc.9b01503
AbstractPalladium-catalyzed C-H diarylation of ferrocenes is described. In the presence of 10 mol % Pd(OAc)(2), direct C-H diarylation reactions of commercially available ferrocenecarboxylic acid with aryl iodides proceeded smoothly to afford diarylated ferrocenes bearing a variety of functional groups in moderate to good yields. The carboxylic group could also act as a remote directing group to result in the third arylation on the other Cp ring of ferrocene.
Indexed BySCI
Language英语
Funding ProjectScience and Technology Commission of Shanghai Municipality[18JC1411302]
WOS Research AreaChemistry
WOS SubjectChemistry, Organic
WOS IDWOS:000492118100041
PublisherAMER CHEMICAL SOC
EISSN1520-6904
WOS KeywordPLANAR CHIRAL FERROCENES ; DIRECT ORTHO-ARYLATION ; ENANTIOSELECTIVE SYNTHESIS ; ASYMMETRIC CATALYSIS ; BENZOIC-ACIDS ; LIGAND ; REDOX ; ACTIVATION ; FUNCTIONALIZATION ; 8-AMINOQUINOLINE
Original Document TypeArticle
Citation statistics
Cited Times [WOS]:0   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://kms.shanghaitech.edu.cn/handle/2MSLDSTB/80517
Collection物质科学与技术学院_硕士生
物质科学与技术学院_特聘教授组_游书力组
Corresponding AuthorGu, Qing; You, Shu-Li
Affiliation1.Chinese Acad Sci, Shanghai Inst Organ Chem, Ctr Excellence Mol Synth, State Key Lab Organometall Chem, 345 Lingling Lu, Shanghai 200032, Peoples R China
2.Cent China Normal Univ, Coll Chem, Minist Educ, Key Lab Pesticide & Chem Biol, Wuhan 430079, Hubei, Peoples R China
3.ShanghaiTech Univ, Sch Phys Sci & Technol, 100 Haike Rd, Shanghai 201210, Peoples R China
Corresponding Author AffilicationSchool of Physical Science and Technology
Recommended Citation
GB/T 7714
Xiang, Jia-Chen,Wu, Zhi-Jie,Gu, Qing,et al. Palladium-Catalyzed C-H Diarylation of Ferrocenecarboxylic Acids with Aryl Iodides[J]. JOURNAL OF ORGANIC CHEMISTRY,2019,84(20):13144-13149.
APA Xiang, Jia-Chen,Wu, Zhi-Jie,Gu, Qing,&You, Shu-Li.(2019).Palladium-Catalyzed C-H Diarylation of Ferrocenecarboxylic Acids with Aryl Iodides.JOURNAL OF ORGANIC CHEMISTRY,84(20),13144-13149.
MLA Xiang, Jia-Chen,et al."Palladium-Catalyzed C-H Diarylation of Ferrocenecarboxylic Acids with Aryl Iodides".JOURNAL OF ORGANIC CHEMISTRY 84.20(2019):13144-13149.
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