Strategies on the construction of 1,2-branched trans-beta-glycosidic linkages and their applications in the synthesis of saponins

doi:10.1080/07328303.2019.1642345

	Strategies on the construction of 1,2-branched trans-beta-glycosidic linkages and their applications in the synthesis of saponins
	Zhu, Dapeng 1; Geng, Mingyu 1; Yang, Fuzhu2 ; Yu, Biao 1
	2019-07-23
发表期刊	JOURNAL OF CARBOHYDRATE CHEMISTRY (IF:1.2[JCR-2023],1.3[5-Year])
ISSN	0732-8303
发表状态	已发表
DOI	10.1080/07328303.2019.1642345
摘要	General strategies on the construction of 1,2-branched trans-beta-glycosidic linkages and the corresponding logics are discussed herein. Linear strategies usually require a temporary acyl protecting group at C2-O position of the glycosylation donors to secure the requisite beta-selective glycosylation. Convergent strategies involve selective formation of the trans-beta-glycosidic linkages in the absence of neighboring participation, wherein solvent participation, invertive glycosylation, as well as other effects have to be exploited to achieve the beta-selective glycosylation. These strategies are illustrated by representative applications in the synthesis of saponins.
关键词	1 2-branched trans-beta-glycosidic linkage glycosylation protecting groups saponin solvent effect
收录类别	SCI ; SCIE
语种	英语
资助项目	Shanghai Sailing Program[19YF1458400]
WOS研究方向	Biochemistry & Molecular Biology ; Chemistry
WOS类目	Biochemistry & Molecular Biology ; Chemistry, Organic
WOS记录号	WOS:000478192900001
出版者	TAYLOR & FRANCIS INC
WOS关键词	ACID-BASE CATALYSIS ; GOLD(I)-CATALYZED GLYCOSYLATION ; BRANCHED OLIGOSACCHARIDE ; CONVERGENT SYNTHESIS ; PROTECTING GROUPS ; REMOTE POSITIONS ; 1ST SYNTHESIS ; ECHINOSIDE-B ; DONORS ; SOLAMARGINE
原始文献类型	Review ; Early Access
引用统计	正在获取...
文献类型	期刊论文
条目标识符	https://kms.shanghaitech.edu.cn/handle/2MSLDSTB/61142
专题	物质科学与技术学院_硕士生
通讯作者	Yu, Biao
作者单位	1.Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Bioorgan & Nat Prod Chem, 345 Lingling Rd, Shanghai 200032, Peoples R China 2.ShanghaiTech Univ, Sch Phys Sci & Technol, Shanghai, Peoples R China
推荐引用方式 GB/T 7714	Zhu, Dapeng,Geng, Mingyu,Yang, Fuzhu,et al. Strategies on the construction of 1,2-branched trans-beta-glycosidic linkages and their applications in the synthesis of saponins[J]. JOURNAL OF CARBOHYDRATE CHEMISTRY,2019.
APA	Zhu, Dapeng,Geng, Mingyu,Yang, Fuzhu,&Yu, Biao.(2019).Strategies on the construction of 1,2-branched trans-beta-glycosidic linkages and their applications in the synthesis of saponins.JOURNAL OF CARBOHYDRATE CHEMISTRY.
MLA	Zhu, Dapeng,et al."Strategies on the construction of 1,2-branched trans-beta-glycosidic linkages and their applications in the synthesis of saponins".JOURNAL OF CARBOHYDRATE CHEMISTRY (2019).