Green synthesis of cavity-containing manganese oxides with superior catalytic performance in toluene oxidation

doi:10.1016/j.apcata.2019.06.005

KMS > 物质科学与技术学院 > PI研究组 > Osamu Terasaki组

	Green synthesis of cavity-containing manganese oxides with superior catalytic performance in toluene oxidation
	Garcia, Tomas 1; Manuel Lopez, Jose 1; Mayoral, Alvaro2 ; Zhang, Yaping2 ; Arenal, Raul 3,4; Alonso-Dominguez, Daniel 5; Pilar Pico, Maria 6; Luisa Lopez, Maria 5; Dejoz, Ana 7; Alvarez-Serrano, Inmaculada 5; Sanchis, Rut 7; Solsona, Benjamin 7
	2019-07-25
发表期刊	APPLIED CATALYSIS A-GENERAL (IF:4.7[JCR-2023],4.8[5-Year])
ISSN	0926-860X
卷号	582
发表状态	已发表
DOI	10.1016/j.apcata.2019.06.005
摘要	Manganese oxide prepared by a simple hydrothermal method is highly active and stable in both lab and quasi industrial conditions for the total oxidation of toluene, achieving total conversion at only 175 degrees C in the absence of water and at 150 degrees C in the presence of 4 mol % water. Moreover, this performance is stable for at least 6 cycles. The enhanced catalytic performance has been related to the presence of highly reactive oxygen surface species. This species are probably promoted by Mn3O4 nanoparticles with Mn3+ at the tetragonal distorted cationic sites, likely compensated by structural water at the anionic sites. The presence of structural water can be related to the formation of internal cavities/vesicles in the Mn3O4 crystalline structure.
关键词	Manganese oxide Cavities Structural water Toluene VOCs oxidation
收录类别	EI ; SCIE ; SCI
语种	英语
资助项目	European Union H2020 program "ESTEEM3"[823717]
WOS研究方向	Chemistry ; Environmental Sciences & Ecology
WOS类目	Chemistry, Physical ; Environmental Sciences
WOS记录号	WOS:000477790800015
出版者	ELSEVIER
EI入藏号	20192607089125
EI主题词	Manganese oxide ; Manganese removal (water treatment) ; Oxidation ; Oxides ; Toluene
EI分类号	Water Treatment Techniques:445.1 ; Chemical Reactions:802.2 ; Chemical Agents and Basic Industrial Chemicals:803 ; Chemical Products Generally:804 ; Organic Compounds:804.1
WOS关键词	VOLATILE ORGANIC-COMPOUNDS ; HYDROTHERMAL SYNTHESIS ; METAL-OXIDE ; MN3O4 ; COMBUSTION ; MORPHOLOGY ; NANOPARTICLES ; BENZENE ; FACILE ; COPPER
原始文献类型	Article
引用统计	正在获取...
文献类型	期刊论文
条目标识符	https://kms.shanghaitech.edu.cn/handle/2MSLDSTB/57624
专题	物质科学与技术学院_PI研究组_Osamu Terasaki组物质科学与技术学院_博士生
通讯作者	Garcia, Tomas; Alvarez-Serrano, Inmaculada; Solsona, Benjamin
作者单位	1.Inst Carboquim ICB CSIC, C Miguel Luesma 4, Zaragoza 50018, Spain 2.ShanghaiTech Univ, Sch Phys Sci & Technol, Ctr High Resolut Electron Microscopy ChEM, 393 Middle Huaxia Rd, Shanghai 201210, Peoples R China 3.Univ Zaragoza, Inst Nanociencia Aragon, Lab Microscopias Avanzadas, Zaragoza 50018, Spain 4.ARAID Fdn, Zaragoza 50018, Spain 5.Univ Complutense Madrid, Fac Ciencias Quim, Dept Quim Inorgan, E-28040 Madrid, Spain 6.Sepiolsa, Avda Acero 14-16,Pol UP-1 Miralcampo, Azuqueca De Henares 19200, Spain 7.Univ Valencia, ETSE, Dept Engn Quim, Av Univ, E-46100 Valencia, Spain
推荐引用方式 GB/T 7714	Garcia, Tomas,Manuel Lopez, Jose,Mayoral, Alvaro,et al. Green synthesis of cavity-containing manganese oxides with superior catalytic performance in toluene oxidation[J]. APPLIED CATALYSIS A-GENERAL,2019,582.
APA	Garcia, Tomas.,Manuel Lopez, Jose.,Mayoral, Alvaro.,Zhang, Yaping.,Arenal, Raul.,...&Solsona, Benjamin.(2019).Green synthesis of cavity-containing manganese oxides with superior catalytic performance in toluene oxidation.APPLIED CATALYSIS A-GENERAL,582.
MLA	Garcia, Tomas,et al."Green synthesis of cavity-containing manganese oxides with superior catalytic performance in toluene oxidation".APPLIED CATALYSIS A-GENERAL 582(2019).