Ni-Catalyzed Reductive Carbonylation of Ethylene with CO2 and Methanol: Potential for in situ CO2 Capture and Conversion

doi:10.1039/d4gc06460g

	Ni-Catalyzed Reductive Carbonylation of Ethylene with CO2 and Methanol: Potential for in situ CO2 Capture and Conversion
	Yuqi, Yang1,2 ; Xiaofang, Liu 1; Haozhi, Zhou1,2 ; Junjun, Chen 1; Yuli, Lai1,2 ; Shunan, Zhang1,2 ; Hu, Luo 1; Hui, Wang 1; Yuhan, Sun1,2
	2025
发表期刊	GREEN CHEMISTRY (IF:9.3[JCR-2023],9.3[5-Year])
ISSN	1463-9262
EISSN	1463-9270
卷号	27 期号:17 页码:4706-4712
发表状态	已发表
DOI	10.1039/d4gc06460g
摘要	Reductive transformation of CO2 using green hydrogen or methanol enables the production of industrially significant chemicals such as carboxylic acid esters, which, however, is hindered by the dependence on noble metal catalysts and the use of halide additives. Here we report a robust non-noble metal-based, halide-free catalytic system for the reductive methoxycarbonylation of ethylene with CO2/MeOH. This system achieves a turnover number of up to 110 for methyl propionate, a key precursor in polymethyl methacrylate production, showing a better performance than conventional noble-metal-based systems. Remarkably, the present system exhibits moderate performance under simulated flue gas containing NOx and SOx, demonstrating the potential for in situ CO2 capture and conversion into value-added chemicals, promoting green and sustainable development.The success of the strategy lies in the unprecedented in situ formation and alcoholytic ring-opening of a five-membered nickelalactone, effectively bypassing the conventional but challenging CO2-to-CO-carbonylation pathway. Notably, this protocol offers a process free from noble metals, halide/acid additives, and strong/expensive reductants, for the production of next-generation CO2-based polymers.
关键词	Carbonylation Catalysis Metal halides Acid ester Catalytic system Halide additives Halide-free Methoxycarbonylation Noble metal catalysts Performance Reductive carbonylation Reductive transformations Turnover number
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收录类别	SCI ; EI
语种	英语
资助项目	National Basic Research Program of China (973 Program)[2022YFB4101900] ; National Key R&D Program of China["22478409","22308215","22279158","22108289"]
WOS研究方向	Chemistry ; Science & Technology - Other Topics
WOS类目	Chemistry, Multidisciplinary ; Green & Sustainable Science & Technology
WOS记录号	WOS:001458846500001
出版者	ROYAL SOC CHEMISTRY
EI入藏号	20251518199617
EI主题词	Kyoto Protocol
EI分类号	802.2 Chemical Reactions ; 804 Chemical Products ; 1501 Sustainability ; 1502.1.1.1 Air Pollution
原始文献类型	Article in Press
文献类型	期刊论文
条目标识符	https://kms.shanghaitech.edu.cn/handle/2MSLDSTB/507136
专题	物质科学与技术学院物质科学与技术学院_特聘教授组_孙予罕组物质科学与技术学院_硕士生物质科学与技术学院_博士生 2060研究院_公共科研平台_低碳转化利用系统研究组
通讯作者	Xiaofang, Liu; Hui, Wang; Yuhan, Sun
作者单位	1.Shanghai Advanced Research Institute 2.ShanghaiTech University
第一作者单位	上海科技大学
通讯作者单位	上海科技大学
推荐引用方式 GB/T 7714	Yuqi, Yang,Xiaofang, Liu,Haozhi, Zhou,et al. Ni-Catalyzed Reductive Carbonylation of Ethylene with CO2 and Methanol: Potential for in situ CO2 Capture and Conversion[J]. GREEN CHEMISTRY,2025,27(17):4706-4712.
APA	Yuqi, Yang.,Xiaofang, Liu.,Haozhi, Zhou.,Junjun, Chen.,Yuli, Lai.,...&Yuhan, Sun.(2025).Ni-Catalyzed Reductive Carbonylation of Ethylene with CO2 and Methanol: Potential for in situ CO2 Capture and Conversion.GREEN CHEMISTRY,27(17),4706-4712.
MLA	Yuqi, Yang,et al."Ni-Catalyzed Reductive Carbonylation of Ethylene with CO2 and Methanol: Potential for in situ CO2 Capture and Conversion".GREEN CHEMISTRY 27.17(2025):4706-4712.