Direct synthesis of covalent triazine-based frameworks (CTFs) through aromatic nucleophilic substitution reactions

doi:10.1039/c9ra02934f

	Direct synthesis of covalent triazine-based frameworks (CTFs) through aromatic nucleophilic substitution reactions
	Chen, Tao 1,2; Li, Wen-Qian 1,2; Hu, Wei-Bo 1; Hu, Wen-Jing 1; Liu, Yahu A.3; Yang, Hui1,4 ; Wen, Ke1,4
	2019-06-09
发表期刊	RSC ADVANCES
ISSN	2046-2069
卷号	9 期号:31 页码:18008-18012
发表状态	已发表
DOI	10.1039/c9ra02934f
摘要	Despite extensive efforts, only three main strategies have been developed to synthesize covalent triazine-based frameworks (CTFs) thus far. We report herein a totally new synthetic strategy which allows C-C bonds in the CTFs to be formed through aromatic nucleophilic substitution reactions. The as-synthesized CTF-1 and CTF-2 exhibited photocatalytic water splitting activity comparable to the CTFs made using ionothermal or Bronsted acid-catalyzed polymerization. Interestingly, CTF-2 distinguished itself by its two-photon fluorescence (emission at similar to 530 nm under irradiation at either 400 nm or 800 nm).
收录类别	SCI ; SCIE ; EI
语种	英语
资助项目	Young Innovation Fund of Shanghai Advanced Research Institute[171008]
WOS研究方向	Chemistry
WOS类目	Chemistry, Multidisciplinary
WOS记录号	WOS:000471914300057
出版者	ROYAL SOC CHEMISTRY
EI入藏号	20192507076752
EI主题词	Photocatalytic activity ; Substitution reactions
EI分类号	Chemical Reactions:802.2 ; Organic Compounds:804.1
WOS关键词	NITROGEN-DOPED GRAPHENE ; POROUS ORGANIC POLYMERS ; HYDROGEN STORAGE ; DESIGN ; EFFICIENT ; CO2 ; TEMPERATURE ; OXYGEN ; POLYMERIZATION ; FLUORESCENT
原始文献类型	Article
引用统计
文献类型	期刊论文
条目标识符	https://kms.shanghaitech.edu.cn/handle/2MSLDSTB/49492
专题	物质科学与技术学院_特聘教授组_文珂组物质科学与技术学院_特聘教授组_杨辉组
通讯作者	Hu, Wei-Bo; Yang, Hui; Wen, Ke
作者单位	1.Chinese Acad Sci, Shanghai Adv Res Inst, Shanghai 201210, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.ChemBridge Res Labs, Med Chem, San Diego, CA 92127 USA 4.Shanghai Tech Univ, Sch Phys Sci & Technol, Shanghai 201210, Peoples R China
通讯作者单位	物质科学与技术学院
推荐引用方式 GB/T 7714	Chen, Tao,Li, Wen-Qian,Hu, Wei-Bo,et al. Direct synthesis of covalent triazine-based frameworks (CTFs) through aromatic nucleophilic substitution reactions[J]. RSC ADVANCES,2019,9(31):18008-18012.
APA	Chen, Tao.,Li, Wen-Qian.,Hu, Wei-Bo.,Hu, Wen-Jing.,Liu, Yahu A..,...&Wen, Ke.(2019).Direct synthesis of covalent triazine-based frameworks (CTFs) through aromatic nucleophilic substitution reactions.RSC ADVANCES,9(31),18008-18012.
MLA	Chen, Tao,et al."Direct synthesis of covalent triazine-based frameworks (CTFs) through aromatic nucleophilic substitution reactions".RSC ADVANCES 9.31(2019):18008-18012.