Atom-Economic Synthesis of Zeolites

doi:10.1021/jacs.4c11264

	Atom-Economic Synthesis of Zeolites
	Deng, Lifan 1; Ma, Ye2 ; Zai, Tianming 1; Yi, Xianfeng 3; Tong, Yan 4; Hui, Yu 1; Fan, Kai 1; Wu, Qinming 1; Ma, Yanhang2 ; Liu, Xiaolong 4; Liu, Weiliao 5; Sheng, Na 5; Wang, Han 5; Zheng, Anmin 6; Wang, Liang 1; Xiao, Feng-Shou 1
	2024-10-01
发表期刊	JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (IF:14.4[JCR-2023],14.8[5-Year])
ISSN	0002-7863
EISSN	1520-5126
卷号	146 期号:42 页码:29115-29122
发表状态	已发表
DOI	10.1021/jacs.4c11264
摘要	Zeolites are typically synthesized in the presence of strong alkaline or fluoride species, which is not atom-economic for zeolite synthesis due to the high solubility of strong alkaline and fluoride species to silica. One of the solutions for this issue is to reduce solubility of silica in the zeolite synthesis, but it is challenging. Herein, we show that nucleation and growth of zeolites can occur under near neutral conditions, giving an atom-economical synthesis of zeolites with almost full silica utilization due to very low silica solubility. Compared to conventional hydrothermal synthesis, this work both enhances the zeolite yield and reduces waste emissions, even water zero emission. Particularly, structural defects (terminal silanols) in zeolites are obviously lowered, thus giving high thermal and hydrothermal stabilities and good performance in the Beckmann rearrangement.
关键词	Alkalinity Hydrothermal synthesis Alkalines Atom economic High solubility Near-neutral conditions Nucleation and growth Structural defect Synthesised Waste emission Zeolite synthesis Zero emission
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收录类别	EI ; SCI
语种	英语
资助项目	Natural Science Foundation of Wuhan[2024040701010058] ; null[22288101] ; null[U21B20101] ; null[21932006] ; null[22172141] ; null[LR24B030001]
WOS研究方向	Chemistry
WOS类目	Chemistry, Multidisciplinary
WOS记录号	WOS:001336901400001
出版者	AMER CHEMICAL SOC
EI入藏号	20244217224379
EI主题词	Solubility
EI分类号	801 Chemistry ; 801.3 Colloid Chemistry ; 802.2 Chemical Reactions
原始文献类型	Journal article (JA)
引用统计	正在获取...
文献类型	期刊论文
条目标识符	https://kms.shanghaitech.edu.cn/handle/2MSLDSTB/436535
专题	物质科学与技术学院物质科学与技术学院_PI研究组_马延航组
通讯作者	Wu, Qinming; Xiao, Feng-Shou
作者单位	1.Key Laboratory of Biomass Chemical Engineering, Ministry of Education, College of Chemical and Biological Engineering, Key Laboratory of Applied Chemistry of Zhejiang Province, Zhejiang University, Hangzhou; 310028, China; 2.School of Physical Science and Technology, ShanghaiTech University, Shanghai; 201210, China; 3.State Key Laboratory of Magnetic Resonance and Atomic and Molecular Physics, National Center for Magnetic Resonance in Wuhan, Wuhan Institute of Physics and Mathematics, Innovation Academy for Precision Measurement Science and Technology, Chinese Academy of Sciences, Wuhan; 430071, China; 4.School of Materials, Sun Yat-Sen University, Guangzhou; 510275, China; 5.Zhejiang Hengyi Petrochemical Research Institute Co., Ltd., Hangzhou; 310027, China; 6.Interdisciplinary Institute of NMR and Molecular Sciences, School of Chemistry and Chemical Engineering, the State Key Laboratory of Refractories and Metallurgy, Wuhan University of Science and Technology, Wuhan; 430081, China
推荐引用方式 GB/T 7714	Deng, Lifan,Ma, Ye,Zai, Tianming,et al. Atom-Economic Synthesis of Zeolites[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2024,146(42):29115-29122.
APA	Deng, Lifan.,Ma, Ye.,Zai, Tianming.,Yi, Xianfeng.,Tong, Yan.,...&Xiao, Feng-Shou.(2024).Atom-Economic Synthesis of Zeolites.JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,146(42),29115-29122.
MLA	Deng, Lifan,et al."Atom-Economic Synthesis of Zeolites".JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 146.42(2024):29115-29122.