ShanghaiTech University Knowledge Management System
| Asymmetric Transformations of alpha-Hydroxy Enamides Catalyzed by Chiral Bronsted Acids | |
| 2019-05 | |
| 发表期刊 | SYNLETT (IF:1.7[JCR-2023],1.6[5-Year]) |
| ISSN | 0936-5214 |
| 卷号 | 30期号:8页码:869-874 |
| 发表状态 | 已发表 |
| DOI | 10.1055/s-0037-1612078 |
| 摘要 | 2-Aminoallyl cations are reactive intermediates that undergo diverse reactions, such as cycloadditions, direct nucleophilic additions, Nazarov electrocyclizations, and rearrangements. We review recent development in asymmetric catalytic reactions (nucleophilic additions and Nazarov electrocyclizations) based on chiral counteranion-paired 2aminoallyl cation intermediates generated through activation of a-hydroxy enamides in the presence of chiral Bronsted acid catalysts. With an understanding of their asymmetric catalysis modes and mechanisms, we expect more asymmetric catalytic reactions will be developed on the basis of this strategy in the near future. |
| 关键词 | aminoallyl cations hydroxy enamides chiral anion catalysis Bronsted acids indole addition Nazarov electrocyclization |
| 收录类别 | SCI ; SCIE |
| 语种 | 英语 |
| 资助项目 | NSFC[21702138] |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Organic |
| WOS记录号 | WOS:000467271100001 |
| 出版者 | GEORG THIEME VERLAG KG |
| WOS关键词 | ACTIVATION ; CYCLOADDITIONS ; MODE |
| 原始文献类型 | Article |
| 引用统计 | 正在获取...
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| 文献类型 | 期刊论文 |
| 条目标识符 | https://kms.shanghaitech.edu.cn/handle/2MSLDSTB/40891 |
| 专题 | 物质科学与技术学院_PI研究组_杨晓瑜组 物质科学与技术学院_硕士生 |
| 通讯作者 | Yang, Xiaoyu |
| 作者单位 | ShanghaiTech Univ, Sch Phys Sci & Technol, Shanghai 201210, Peoples R China |
| 第一作者单位 | 物质科学与技术学院 |
| 通讯作者单位 | 物质科学与技术学院 |
| 第一作者的第一单位 | 物质科学与技术学院 |
| 推荐引用方式 GB/T 7714 | Rajkumar, Subramani,Wang, Jiawen,Yang, Xiaoyu. Asymmetric Transformations of alpha-Hydroxy Enamides Catalyzed by Chiral Bronsted Acids[J]. SYNLETT,2019,30(8):869-874. |
| APA | Rajkumar, Subramani,Wang, Jiawen,&Yang, Xiaoyu.(2019).Asymmetric Transformations of alpha-Hydroxy Enamides Catalyzed by Chiral Bronsted Acids.SYNLETT,30(8),869-874. |
| MLA | Rajkumar, Subramani,et al."Asymmetric Transformations of alpha-Hydroxy Enamides Catalyzed by Chiral Bronsted Acids".SYNLETT 30.8(2019):869-874. |
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