Two Deep Ultraviolet Hydrated Borate Crystals: Centrosymmetric LiRbB5O8(OH)center dot H2O and Non-Centrosymmetric K2B5O8(OH)center dot 2H(2)O

doi:10.1021/acs.cgd.9b00365

	Two Deep Ultraviolet Hydrated Borate Crystals: Centrosymmetric LiRbB5O8(OH)center dot H2O and Non-Centrosymmetric K2B5O8(OH)center dot 2H(2)O
	Shi, Yutong1,2,3,4 ; Luo, Min 2; Lin, Chensheng 2; Peng, Guang 2; Ye, Ning1,2
	2019-05
发表期刊	CRYSTAL GROWTH & DESIGN (IF:3.2[JCR-2023],3.2[5-Year])
ISSN	1528-7483
卷号	19 期号:5 页码:3052-3059
发表状态	已发表
DOI	10.1021/acs.cgd.9b00365
摘要	Two hydrated borate crystals, namely, centrosymmetric LiRbB5O8(OH)center dot H2O (LRB) and non-centrosymmetric K2B5O8(OH)center dot 2H(2)O (K2B5), were successfully synthesized by a solvothermal technique. Although two titled compounds have the same fundamental building block B5O10(OH), the distinct linkage modes make them exhibit completely different structures. Compounds LRB and K2B5 crystallize in the nonpolar space group of P2(1)/n and polar space group Pna2(1), respectively. Thermal analyses of both compounds were performed. Besides, they had short UV cutoff edge (<200 nm) according to UV-vis-NIR diffuse reflectance spectroscopy. Significantly, compound K2B5 exhibited a high laser damage threshold and moderate second harmonic generation intensity (0.84 x KDP). Furthermore, the optical properties and electronic structures of both compounds have been well studied by the density functional theory method.
收录类别	SCI ; SCIE ; EI
语种	英语
资助项目	Youth Innovation Promotion Association CAS[303]
WOS研究方向	Chemistry ; Crystallography ; Materials Science
WOS类目	Chemistry, Multidisciplinary ; Crystallography ; Materials Science, Multidisciplinary
WOS记录号	WOS:000466987600062
出版者	AMER CHEMICAL SOC
WOS关键词	NONLINEAR-OPTICAL MATERIAL ; GENERATION ; CARBONATE ; MINERALS ; DESIGN ; SIZE
原始文献类型	Article
引用统计	正在获取...
文献类型	期刊论文
条目标识符	https://kms.shanghaitech.edu.cn/handle/2MSLDSTB/40880
专题	物质科学与技术学院_硕士生物质科学与技术学院_特聘教授组_叶宁组
通讯作者	Luo, Min; Ye, Ning
作者单位	1.ShanghaiTech Univ, Sch Phys Sci & Technol, Shanghai 201210, Peoples R China 2.Chinese Acad Sci, Fujian Inst Res Struct Matter, Key Lab Optoelect Mat Chem & Phys, Fuzhou 350002, Fujian, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 4.Chinese Acad Sci, Shanghai Inst Ceram, Shanghai 200050, Peoples R China
第一作者单位	物质科学与技术学院
通讯作者单位	物质科学与技术学院
第一作者的第一单位	物质科学与技术学院
推荐引用方式 GB/T 7714	Shi, Yutong,Luo, Min,Lin, Chensheng,et al. Two Deep Ultraviolet Hydrated Borate Crystals: Centrosymmetric LiRbB5O8(OH)center dot H2O and Non-Centrosymmetric K2B5O8(OH)center dot 2H(2)O[J]. CRYSTAL GROWTH & DESIGN,2019,19(5):3052-3059.
APA	Shi, Yutong,Luo, Min,Lin, Chensheng,Peng, Guang,&Ye, Ning.(2019).Two Deep Ultraviolet Hydrated Borate Crystals: Centrosymmetric LiRbB5O8(OH)center dot H2O and Non-Centrosymmetric K2B5O8(OH)center dot 2H(2)O.CRYSTAL GROWTH & DESIGN,19(5),3052-3059.
MLA	Shi, Yutong,et al."Two Deep Ultraviolet Hydrated Borate Crystals: Centrosymmetric LiRbB5O8(OH)center dot H2O and Non-Centrosymmetric K2B5O8(OH)center dot 2H(2)O".CRYSTAL GROWTH & DESIGN 19.5(2019):3052-3059.